Identification, classification and characterisation of hydrides in Zr alloys

Hydride precipitation in zirconium alloys leads to embrittlement, making it essential to understand their prevalence and stability in the microstructure. Dictionary indexing of Kikuchi patterns, along with orientation relationship analysis and x-ray diffraction, confirmed the presence of both delta and gamma hydride phases in Zircaloy-4. Both phases were found to be stable in recrystallised zirconium, with the gamma phase exhibiting a distinct orientation relationship with the matrix. Delta hydride morphology and orientation were influenced by local stresses, resulting in a change in orientation during precipitation. By analysing the orientation relationships, the evolution of hydride phases could be visualised, providing insights into the room temperature stability of both delta and gamma hydrides.