This paper proposes an Explicit Model Predictive Control (eMPC) for the energy management of an e-vehicle charging station fueled by a photovoltaic plant (PV), a battery energy storage system (BESS), and the electrical grid. The method computes offline an explicit solution of the MPC, which is stored and then used for real time control. Multiparametric programming is used to calculate the explicit solution by mapping the MPC laws as a function of uncertain parameters. In this paper, the uncertainties introduced into the multiparametric programming are the photovoltaic power production, the electricity price, the battery's state of charge, and the electric vehicle power consumption. Moreover, the environmental impact of the charging station ...