The rate of ring opening of α-trialkylsilyloxycyclopropylmethyl radicals is about ten times slower than of the cyclopropylmethyl radical at 298K.</p
Calculated kinetic isotope effects, without tunnelling corrections, for the ring opening of cyclopro...
Rate constants for the ring-opening reactions of cis- and trans-2-methylcyclobutylmethyl, cis- and t...
Article on calculations predicting a large inverse H/D kinetic isotope effect on the rate of tunneli...
The rate of ring opening of α-trialkylsilyloxycyclopropylmethyl radicals is about ten times slower t...
The kinetics of ring openings of a series of eight (trans-2-arylcyclopropyl)methyl radicals (1) were...
The ability of several density-functional theory methods to describe the kinetics and energetics of ...
Rate constants for the ring-opening reactions of cyclobutylmethyl, 1-cyclobutyl-1-methylethyl, and c...
Article on the effects of geminal methyl groups on the tunnelling rates in the ring opening of cyclo...
Following a protocol developed by Mathivanan, Johnston, and Wayner (J. Phys. Chem. 1995, 99, 8190−81...
Kinetic absorption spectroscopy, EPR, and tributylstannane product data indicate that the \u3b1-cycl...
Three independent methods have been employed to estimate the rate constant, k1, for ring-opening of ...
The 1-methyl-, 1-ethoxy-, and 1-chlorocyclopropyl radicals have been observed by low-temperature EPR...
Oxiranylmethyl and 3-methyl-3-oxetanylmethyl radicals were generated from the corresponding bromides...
Article on experimental evidence for heavy-atom tunneling in the ring-opening of cyclopropylcarbinyl...
The ring-opening of cyclopropylcarbinyl radicals has been postulated to proceed via a dipolar transi...
Calculated kinetic isotope effects, without tunnelling corrections, for the ring opening of cyclopro...
Rate constants for the ring-opening reactions of cis- and trans-2-methylcyclobutylmethyl, cis- and t...
Article on calculations predicting a large inverse H/D kinetic isotope effect on the rate of tunneli...
The rate of ring opening of α-trialkylsilyloxycyclopropylmethyl radicals is about ten times slower t...
The kinetics of ring openings of a series of eight (trans-2-arylcyclopropyl)methyl radicals (1) were...
The ability of several density-functional theory methods to describe the kinetics and energetics of ...
Rate constants for the ring-opening reactions of cyclobutylmethyl, 1-cyclobutyl-1-methylethyl, and c...
Article on the effects of geminal methyl groups on the tunnelling rates in the ring opening of cyclo...
Following a protocol developed by Mathivanan, Johnston, and Wayner (J. Phys. Chem. 1995, 99, 8190−81...
Kinetic absorption spectroscopy, EPR, and tributylstannane product data indicate that the \u3b1-cycl...
Three independent methods have been employed to estimate the rate constant, k1, for ring-opening of ...
The 1-methyl-, 1-ethoxy-, and 1-chlorocyclopropyl radicals have been observed by low-temperature EPR...
Oxiranylmethyl and 3-methyl-3-oxetanylmethyl radicals were generated from the corresponding bromides...
Article on experimental evidence for heavy-atom tunneling in the ring-opening of cyclopropylcarbinyl...
The ring-opening of cyclopropylcarbinyl radicals has been postulated to proceed via a dipolar transi...
Calculated kinetic isotope effects, without tunnelling corrections, for the ring opening of cyclopro...
Rate constants for the ring-opening reactions of cis- and trans-2-methylcyclobutylmethyl, cis- and t...
Article on calculations predicting a large inverse H/D kinetic isotope effect on the rate of tunneli...