SULFINYL-CONTROLLED FORMATION OF DIASTEREOISOMERICALLY PURE (OXADIENE)TRICARBONYLIRON(0) COMPLEXES

Regio- and stereoselectivity in long-range asymmetric induction controlled by carbonyliron groups: crystal structures of dicarbonyl-L- (1,2,3,4,5-eta)-1-R-4-methoxycyclohexadienyl iron(1+) hexafluorophosphate(1-) (R = isopropenyl, L = CO), (R=1-styryl, L = CO), (R=1-prop-1-enyl, L = PPh3) and tricarbonyl methyl(2,3,4,5-eta)-2-carbomethoxy-2-(4-methoxy-1-(1 '-methylethenyl)cyclohexadien-1-yl)ethanoate iron(0)

Hudson, R. D. A.
Anson, C. E.
Mahon, M. F.
Stephenson, G. R.

January 2001

The synthesis of alkenyl-extended cyclohexadienyliron complexes is described and reactions are repor...

Reactivity of Tricarbonyl(pentadienyl)iron(1+) Cations: Preparation of an Optically Pure Tricarbonyl(diene)iron Complex via Second-Order Asymmetric Transformation

Donaldson, William
Shang, Leiwei
Rogers, Robin D.

January 1994

Summary: Reactions of tricarbonyl(2,4-dimethylpentadienyl)iron(l+) hexafluorophosphate (1) with sodi...

Synthesis, Structure and Conformation of cis- and trans-(μ-1,6-Dimethylheptalene)bis(tricarbonyliron)

Grimm, Felix W.
Hafner, Klaus
Lindner, Hans Jörg

January 2022

The reaction of 1,6-dimethylheptalene (2) with Fe₂(CO)₉ affords two binuclear iron complexes 4a and ...

SULFINYL-CONTROLLED FORMATION OF DIASTEREOISOMERICALLY PURE (OXADIENE)TRICARBONYLIRON(0) COMPLEXES

IBBOTSON, A
SLAWIN, A M Z
THOMAS, S E
TUSTIN, G J
WILLIAMS, D J

November 1991

The sulphonyl and sulphinyl substituted oxadienes [RS(O)(n)CH = CHC(Me) = O; R = Bu(t), Ph; n = 2,1]...

SULFINYL-CONTROLLED FORMATION OF DIASTEREOISOMERICALLY PURE TRICARBONYL(OXADIENE)IRON(0) COMPLEXES AND A DIASTEREOISOMERICALLY PURE TETRACARBONYL(ALKENE)IRON(0) COMPLEX

IBBOTSON, A
DOSREIS, A C R
SABERI, S P
SLAWIN, A M Z
THOMAS, S E
TUSTIN, G J
WILLIAMS, D J

May 1992

The sulfonyl and sulfinyl substituted oxadienes [RS(O)nCH=CHC(Me)=O; R = Bu(t), Ph; n = 2,1] form st...

Synthesis And Diastereoselective Complexation Of Enantiopure Sulfinyl Dienes: The Preparation Of Sulfinyl Iron(0) Dienes

Paley, Robert S.
De Dios, A.
Estroff, Lara Ann, , \u2797
Lafontaine, Jennifer Anne, , \u2793
Montero, C.
McCulley, David James, , \u2796
Rubio, M. B.
Ventura, M. P.
Weers, Heather L., , \u2794
De La Pradilla, R. F.
Castro, S.
Dorado, R.
Morente, M.

September 1997

The preparation of a diverse array of enantiomerically pure 1- and 2-sulfinyl dienes has been achiev...

CONVERSION OF (VINYLKETENE)TRICARBONYLIRON(0) COMPLEXES INTO (VINYLALLENE)TRICARBONYLIRON(0) COMPLEXES

Addition of phosphonoacetate anions to (vinylketene)tricarbonyliron(0) complexes gave (vinylallene)t...

1ST SYNTHESIS OF SULFINYL SUBSTITUTED TRICARBONYL(ETA(6)-ARENE)CHROMIUM(0) COMPLEXES

PEREZENCABO, A
PERRIO, S
SLAWIN, A M Z
THOMAS, S E
WIERZCHLEYSKI, A T
WILLIAMS, D J

July 1993

Dimethyldioxirane efficiently oxidises tricarbonylchromium(0) complexes of sulfenyl substituted aren...

Diastereoselective Formation Of An [Eta(4)-(1z)-Sulfinyl Diene]Iron(0) Tricarbonyl Complex. Diastereoselective Allylation Of The Derived Iron Dienal

Paley, Robert S.
Rubio, M. B.
De La Pradilla, R. F.
Dorado, R.
Hundall née Sood, G.
Martínez-Ripoll, M.

October 1996

An enantiomerically pure (1Z,3E)-sulfinyl diene exhibited a high degree of facial selectivity (alpha...

SYNTHESIS OF TRICARBONYLIRON(0) COMPLEXES OF ITACONIC ACID-DERIVATIVES

ALT, C
GRIFFITHS, S L
MARCOS, C F
SALTER, M M
SLAWIN, A M Z
THOMAS, S E
WILLIAMS, D J

January 1993

The products derived from [Fe2(CO)9] and alkenes bearing beta-carbonyl groups linked to the alkene v...

Reactivity patterns in cationic tricarbonyliron complexes: crystallographic proof of stereoselectivity in long range asymmetric induction in the 1,3/1 ',2 ' series

Anson, Christopher E.
Hudson, Richard D. A.
Smyth, Donald G.
Stephenson, G. Richard

January 2001

The analysis of patterns of regioselectivity in cyclohexadienyl complexes illustrates the versatilit...

DIASTEREOSELECTIVE FORMATION OF TRICARBONYLIRON(0) COMPLEXES OF 1-AZA-1,3-DIENES BEARING CHIRAL SUBSTITUENTS

Syntheses of two series of novel 1-aza-1,3-dienes bearing chiral substituents on nitrogen [PhCH = CH...

Diastereoselective Allylations Of Enantiopure 3- And 4-Substituted Eta(4)-(1z)-(Sulfinyldienal)Iron(0) Tricarbonyl Complexes

Paley, Robert S.
Estroff, Lara Ann, , \u2797
McCulley, David James, , \u2796
Martinez-Cruz, L. A.
Sanchez, A. J.
Cano, F. H.

April 1998

Diastereoselectivity of allylations of enantiopure 3- and 4-substituted eta(4)-(1Z)-(sulfinyldienal)...

ADDITION OF ALKYNES TO (VINYLKETENE)TRICARBONYLIRON(0) COMPLEXES

MORRIS, K G
SABERI, S P
SLAWIN, A M Z
THOMAS, S E
WILLIAMS, D J

December 1992

Alkynes add to (vinylketene)tricarbonyliron(0) complexes to generate stable adducts; addition of uns...

Synthesis and Applications of Tricarbonyliron Complexes of Dendralenes

Toombs-Ruane, Henry
Osinski, Nik
Fallon, Thomas
Wills, Cindy
Willis, Anthony
Paddon-Row, Michael
Sherburn, Michael

February 2016

[3]Dendralene and [4]dendralene are converted smoothly into tricarbonyliron complexes. The structure...

Regio- and stereoselectivity in long-range asymmetric induction controlled by carbonyliron groups: crystal structures of dicarbonyl-L- (1,2,3,4,5-eta)-1-R-4-methoxycyclohexadienyl iron(1+) hexafluorophosphate(1-) (R = isopropenyl, L = CO), (R=1-styryl, L = CO), (R=1-prop-1-enyl, L = PPh3) and tricarbonyl methyl(2,3,4,5-eta)-2-carbomethoxy-2-(4-methoxy-1-(1 '-methylethenyl)cyclohexadien-1-yl)ethanoate iron(0)

Hudson, R. D. A.
Anson, C. E.
Mahon, M. F.
Stephenson, G. R.

January 2001

The synthesis of alkenyl-extended cyclohexadienyliron complexes is described and reactions are repor...

Reactivity of Tricarbonyl(pentadienyl)iron(1+) Cations: Preparation of an Optically Pure Tricarbonyl(diene)iron Complex via Second-Order Asymmetric Transformation

Donaldson, William
Shang, Leiwei
Rogers, Robin D.

January 1994

Summary: Reactions of tricarbonyl(2,4-dimethylpentadienyl)iron(l+) hexafluorophosphate (1) with sodi...

Synthesis, Structure and Conformation of cis- and trans-(μ-1,6-Dimethylheptalene)bis(tricarbonyliron)

Grimm, Felix W.
Hafner, Klaus
Lindner, Hans Jörg

January 2022

The reaction of 1,6-dimethylheptalene (2) with Fe₂(CO)₉ affords two binuclear iron complexes 4a and ...

SULFINYL-CONTROLLED FORMATION OF DIASTEREOISOMERICALLY PURE (OXADIENE)TRICARBONYLIRON(0) COMPLEXES

IBBOTSON, A
SLAWIN, A M Z
THOMAS, S E
TUSTIN, G J
WILLIAMS, D J

November 1991

The sulphonyl and sulphinyl substituted oxadienes [RS(O)(n)CH = CHC(Me) = O; R = Bu(t), Ph; n = 2,1]...

SULFINYL-CONTROLLED FORMATION OF DIASTEREOISOMERICALLY PURE TRICARBONYL(OXADIENE)IRON(0) COMPLEXES AND A DIASTEREOISOMERICALLY PURE TETRACARBONYL(ALKENE)IRON(0) COMPLEX

IBBOTSON, A
DOSREIS, A C R
SABERI, S P
SLAWIN, A M Z
THOMAS, S E
TUSTIN, G J
WILLIAMS, D J

May 1992

The sulfonyl and sulfinyl substituted oxadienes [RS(O)nCH=CHC(Me)=O; R = Bu(t), Ph; n = 2,1] form st...

Synthesis And Diastereoselective Complexation Of Enantiopure Sulfinyl Dienes: The Preparation Of Sulfinyl Iron(0) Dienes

Paley, Robert S.
De Dios, A.
Estroff, Lara Ann, , \u2797
Lafontaine, Jennifer Anne, , \u2793
Montero, C.
McCulley, David James, , \u2796
Rubio, M. B.
Ventura, M. P.
Weers, Heather L., , \u2794
De La Pradilla, R. F.
Castro, S.
Dorado, R.
Morente, M.

September 1997

The preparation of a diverse array of enantiomerically pure 1- and 2-sulfinyl dienes has been achiev...

CONVERSION OF (VINYLKETENE)TRICARBONYLIRON(0) COMPLEXES INTO (VINYLALLENE)TRICARBONYLIRON(0) COMPLEXES

Addition of phosphonoacetate anions to (vinylketene)tricarbonyliron(0) complexes gave (vinylallene)t...

1ST SYNTHESIS OF SULFINYL SUBSTITUTED TRICARBONYL(ETA(6)-ARENE)CHROMIUM(0) COMPLEXES

PEREZENCABO, A
PERRIO, S
SLAWIN, A M Z
THOMAS, S E
WIERZCHLEYSKI, A T
WILLIAMS, D J

July 1993

Dimethyldioxirane efficiently oxidises tricarbonylchromium(0) complexes of sulfenyl substituted aren...

Diastereoselective Formation Of An [Eta(4)-(1z)-Sulfinyl Diene]Iron(0) Tricarbonyl Complex. Diastereoselective Allylation Of The Derived Iron Dienal

Paley, Robert S.
Rubio, M. B.
De La Pradilla, R. F.
Dorado, R.
Hundall née Sood, G.
Martínez-Ripoll, M.

October 1996

An enantiomerically pure (1Z,3E)-sulfinyl diene exhibited a high degree of facial selectivity (alpha...

SYNTHESIS OF TRICARBONYLIRON(0) COMPLEXES OF ITACONIC ACID-DERIVATIVES

ALT, C
GRIFFITHS, S L
MARCOS, C F
SALTER, M M
SLAWIN, A M Z
THOMAS, S E
WILLIAMS, D J

January 1993

The products derived from [Fe2(CO)9] and alkenes bearing beta-carbonyl groups linked to the alkene v...

Reactivity patterns in cationic tricarbonyliron complexes: crystallographic proof of stereoselectivity in long range asymmetric induction in the 1,3/1 ',2 ' series

Anson, Christopher E.
Hudson, Richard D. A.
Smyth, Donald G.
Stephenson, G. Richard

January 2001

The analysis of patterns of regioselectivity in cyclohexadienyl complexes illustrates the versatilit...

DIASTEREOSELECTIVE FORMATION OF TRICARBONYLIRON(0) COMPLEXES OF 1-AZA-1,3-DIENES BEARING CHIRAL SUBSTITUENTS

Syntheses of two series of novel 1-aza-1,3-dienes bearing chiral substituents on nitrogen [PhCH = CH...

Diastereoselective Allylations Of Enantiopure 3- And 4-Substituted Eta(4)-(1z)-(Sulfinyldienal)Iron(0) Tricarbonyl Complexes

Paley, Robert S.
Estroff, Lara Ann, , \u2797
McCulley, David James, , \u2796
Martinez-Cruz, L. A.
Sanchez, A. J.
Cano, F. H.

April 1998

Diastereoselectivity of allylations of enantiopure 3- and 4-substituted eta(4)-(1Z)-(sulfinyldienal)...

ADDITION OF ALKYNES TO (VINYLKETENE)TRICARBONYLIRON(0) COMPLEXES

MORRIS, K G
SABERI, S P
SLAWIN, A M Z
THOMAS, S E
WILLIAMS, D J

December 1992

Alkynes add to (vinylketene)tricarbonyliron(0) complexes to generate stable adducts; addition of uns...

Synthesis and Applications of Tricarbonyliron Complexes of Dendralenes

Toombs-Ruane, Henry
Osinski, Nik
Fallon, Thomas
Wills, Cindy
Willis, Anthony
Paddon-Row, Michael
Sherburn, Michael

February 2016

[3]Dendralene and [4]dendralene are converted smoothly into tricarbonyliron complexes. The structure...

Regio- and stereoselectivity in long-range asymmetric induction controlled by carbonyliron groups: crystal structures of dicarbonyl-L- (1,2,3,4,5-eta)-1-R-4-methoxycyclohexadienyl iron(1+) hexafluorophosphate(1-) (R = isopropenyl, L = CO), (R=1-styryl, L = CO), (R=1-prop-1-enyl, L = PPh3) and tricarbonyl methyl(2,3,4,5-eta)-2-carbomethoxy-2-(4-methoxy-1-(1 '-methylethenyl)cyclohexadien-1-yl)ethanoate iron(0)

Hudson, R. D. A.
Anson, C. E.
Mahon, M. F.
Stephenson, G. R.

January 2001

The synthesis of alkenyl-extended cyclohexadienyliron complexes is described and reactions are repor...

Reactivity of Tricarbonyl(pentadienyl)iron(1+) Cations: Preparation of an Optically Pure Tricarbonyl(diene)iron Complex via Second-Order Asymmetric Transformation

Donaldson, William
Shang, Leiwei
Rogers, Robin D.

January 1994

Summary: Reactions of tricarbonyl(2,4-dimethylpentadienyl)iron(l+) hexafluorophosphate (1) with sodi...

Synthesis, Structure and Conformation of cis- and trans-(μ-1,6-Dimethylheptalene)bis(tricarbonyliron)

Grimm, Felix W.
Hafner, Klaus
Lindner, Hans Jörg

January 2022

The reaction of 1,6-dimethylheptalene (2) with Fe₂(CO)₉ affords two binuclear iron complexes 4a and ...

SULFINYL-CONTROLLED FORMATION OF DIASTEREOISOMERICALLY PURE (OXADIENE)TRICARBONYLIRON(0) COMPLEXES

Abstract

Extracted data

SULFINYL-CONTROLLED FORMATION OF DIASTEREOISOMERICALLY PURE (OXADIENE)TRICARBONYLIRON(0) COMPLEXES

Abstract

Extracted data

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