Flash vacuum pyrolysis of alpha-alkanesulfinyl phosphorus ylides results mainly in extrusion of Ph3P to give thioesters, presumably by 1,2-oxygen transfer in the initially formed sulfinyl carbenes; for alpha-arenesulfinyl ylides loss of Ph3PO to give additional products is also observed.</p
Flash vacuum pyrolysis (FVP) of benzo[c]thiopyran S,S-dioxide 1 results in formation of indene and 2...
A series of 11 amino acid-derived stabilised ylides 12-14 and 16 have been prepared and characterise...
A series of five [(acetyt)(arylcarbabmoyl)methylene]triphenyl-phosphoranes 1a-e and their thiocarbar...
Six alpha-sulfiliyl phosphorus ylides 6 have been prepared and are found upon flash vacuum pyrolysis...
Thermal decomposition of arylmethylsulphonylalkylidenetriphenylphosphoranes results in loss of Ph3P ...
Twelve sulfonyl stabilised phosphorus ylides have been prepared and their behaviour upon flash vacuu...
Flash vacuum pyrolysis of phosphorus ylides stabilised both by ester and sulfinyl groups results mai...
A range of 18 alkoxycarbonyl sulfinyl phosphorus ylides 9 have been prepared and their behaviour upo...
Flash vacuum pyrolysis of sulphonyl- and sulphinyl-stabilised phosphorus ylides results in loss of e...
Seventeen novel alpha-benzotriazolyl-beta-oxo phosphorus ylides 2 have been prepared and characteris...
Fourteen new beta-oxo phosphorus ylides 1-14 bearing o-methoxybenzoyl or o-(methyl-sulfanyl)benzoyl ...
We thank EPSRC (UK) for a studentship to ANG.Ten new oxo-stabilised phosphonium ylides containing su...
Flash vacuum pyrolysis (FVP) of benzo[c]thiopyran S,S-dioxide (1) results in formation of indene and...
Thirteen examples of stabilised alkynoyl ylides 6 have been prepared and are found, upon flash vacuu...
Thermal extrusion of Ph(3)PO from beta-oxoalkylidenetriphenylphosphoranes 4 to give the alkynes 5, w...
Flash vacuum pyrolysis (FVP) of benzo[c]thiopyran S,S-dioxide 1 results in formation of indene and 2...
A series of 11 amino acid-derived stabilised ylides 12-14 and 16 have been prepared and characterise...
A series of five [(acetyt)(arylcarbabmoyl)methylene]triphenyl-phosphoranes 1a-e and their thiocarbar...
Six alpha-sulfiliyl phosphorus ylides 6 have been prepared and are found upon flash vacuum pyrolysis...
Thermal decomposition of arylmethylsulphonylalkylidenetriphenylphosphoranes results in loss of Ph3P ...
Twelve sulfonyl stabilised phosphorus ylides have been prepared and their behaviour upon flash vacuu...
Flash vacuum pyrolysis of phosphorus ylides stabilised both by ester and sulfinyl groups results mai...
A range of 18 alkoxycarbonyl sulfinyl phosphorus ylides 9 have been prepared and their behaviour upo...
Flash vacuum pyrolysis of sulphonyl- and sulphinyl-stabilised phosphorus ylides results in loss of e...
Seventeen novel alpha-benzotriazolyl-beta-oxo phosphorus ylides 2 have been prepared and characteris...
Fourteen new beta-oxo phosphorus ylides 1-14 bearing o-methoxybenzoyl or o-(methyl-sulfanyl)benzoyl ...
We thank EPSRC (UK) for a studentship to ANG.Ten new oxo-stabilised phosphonium ylides containing su...
Flash vacuum pyrolysis (FVP) of benzo[c]thiopyran S,S-dioxide (1) results in formation of indene and...
Thirteen examples of stabilised alkynoyl ylides 6 have been prepared and are found, upon flash vacuu...
Thermal extrusion of Ph(3)PO from beta-oxoalkylidenetriphenylphosphoranes 4 to give the alkynes 5, w...
Flash vacuum pyrolysis (FVP) of benzo[c]thiopyran S,S-dioxide 1 results in formation of indene and 2...
A series of 11 amino acid-derived stabilised ylides 12-14 and 16 have been prepared and characterise...
A series of five [(acetyt)(arylcarbabmoyl)methylene]triphenyl-phosphoranes 1a-e and their thiocarbar...