A hydrogen-bonded adduct containing seven-component supramolecular aggregates

The title compound is a salt, 3,6,9,16,19,22-hexaazatricyclo[22.2.2.2(11,14)]triaconta-1(26),11(29),12,14(30),24,27-hexaene-3,5-dinitrobenzoic acid-methanol (1/4/2), C24H42N64+. -4C(7)H(3)N(2)O(6)(-). 2CH(4)O, in which the cation lies across a centre of inversion and one of the two independent anions is positionally disordered over two sets of atom sites having equal occupancy. The components are linked by four types of N-H . . .O hydrogen bond [N . . .O 2.674 (2)-2.815 (2) Angstrom; N-H . . .O 149-163 degrees] and one type of O-H . . .O hydrogen bond in which the acceptor is disordered over two closely adjacent sites [O . . .O 2.67 (4) and 2.75 (4) Angstrom; O-H . . .O 172 and 173 degrees], forming centrosymmetric seven-component aggregates.