The exploration of the FeF3/FeF2-Hamtetraz-HF system in dimethylformamide by solvothermal synthesis evidences two isostructural 3D hybrid fluoroferrates. They are prepared from the same starting mixture at two different synthesis temperatures: 120 °C for [Hdma]·(Fe4IIFeIIIF8(H2O)2(amtetraz)4) (1) and 140 °C for [Hdma]1.5·(Fe4.5IIFe0.5IIIF7(H2O)(HCOO)(amtetraz)4) (2). Both compounds are characterized by single crystal X-ray diffraction, X-ray thermodiffraction, TGA analysis, Mössbauer spectrometry and SQUID magnetometry. They crystallize in the monoclinic system and are built from two distinct chains connected by aminotetrazolate anions. The first chain ∞(FeIIFN4) is common to 1 and 2 and can be found in numerous fluorides. In the second cha...
With the aim of investigating the impact of lattice solvent on the processability of tetrairon(III) ...
The mixture ZnF2/HFaq./Hamtetraz (Hamtetraz = 5-aminotetrazole) with the molar ratio 10/80/10 reacts...
The Mössbauer spectra of the two crystallographic forms α- and β-(NH4)2FeF5 have been studied in the...
The exploration of the FeF3/FeF2-Hamtetraz-HF system in dimethylformamide by solvothermal synthesis ...
The exploration of the FeF3/FeF2-Hamtetraz-HF system in dimethylformamide by solvothermal synthesis ...
International audienceThe exploration of the composition space diagram of the FeF3/ZnF2–Hamtetraz-HF...
International audienceThree new [H2amtaz]+ iron fluorides are synthesized at 160 °C under microwave ...
A new metal–organic compound FeF6(HAmTAZ)3 which (HAmTAZ = 3-amino-1,2,4-triazole) was hydrothermall...
The exploration of the composition space diagram of the FeF<sub>3</sub>/ZnF<sub>2</sub>–H<i>amtetraz...
Fluorinated tetrairon(III) Single-Molecule Magnets (SMMs) [Fe4(L1)2(dpmF6)6] (1dpmF6), [Fe4(L2)2(dpm...
Metal trifluoroacetates (TFAs) are commonplace precursors for bulk and nanostructured metal fluoride...
A new tetrairon(III) single-molecule magnet with enhanced volatility and processability was obtained...
This paper reports on the synthesis of a new hydroxylammonium fluoroferrate, with the formula $(NH_3...
Copyright © 2022 American Chemical Society. We report the synthesis and characterization of a series...
We have synthesized two new iron complexes that have been structural and magnetically characterized:...
With the aim of investigating the impact of lattice solvent on the processability of tetrairon(III) ...
The mixture ZnF2/HFaq./Hamtetraz (Hamtetraz = 5-aminotetrazole) with the molar ratio 10/80/10 reacts...
The Mössbauer spectra of the two crystallographic forms α- and β-(NH4)2FeF5 have been studied in the...
The exploration of the FeF3/FeF2-Hamtetraz-HF system in dimethylformamide by solvothermal synthesis ...
The exploration of the FeF3/FeF2-Hamtetraz-HF system in dimethylformamide by solvothermal synthesis ...
International audienceThe exploration of the composition space diagram of the FeF3/ZnF2–Hamtetraz-HF...
International audienceThree new [H2amtaz]+ iron fluorides are synthesized at 160 °C under microwave ...
A new metal–organic compound FeF6(HAmTAZ)3 which (HAmTAZ = 3-amino-1,2,4-triazole) was hydrothermall...
The exploration of the composition space diagram of the FeF<sub>3</sub>/ZnF<sub>2</sub>–H<i>amtetraz...
Fluorinated tetrairon(III) Single-Molecule Magnets (SMMs) [Fe4(L1)2(dpmF6)6] (1dpmF6), [Fe4(L2)2(dpm...
Metal trifluoroacetates (TFAs) are commonplace precursors for bulk and nanostructured metal fluoride...
A new tetrairon(III) single-molecule magnet with enhanced volatility and processability was obtained...
This paper reports on the synthesis of a new hydroxylammonium fluoroferrate, with the formula $(NH_3...
Copyright © 2022 American Chemical Society. We report the synthesis and characterization of a series...
We have synthesized two new iron complexes that have been structural and magnetically characterized:...
With the aim of investigating the impact of lattice solvent on the processability of tetrairon(III) ...
The mixture ZnF2/HFaq./Hamtetraz (Hamtetraz = 5-aminotetrazole) with the molar ratio 10/80/10 reacts...
The Mössbauer spectra of the two crystallographic forms α- and β-(NH4)2FeF5 have been studied in the...