Preparation and crystal structures of two forms of trans-[CuCl2{N(H)SPh2}2]; an unusual example of square planar/pseudo-tetrahedral isomerism in a neutral copper(II) complex

Kelly, PF
Slawin, Alexandra Martha Zoya
Waring, KW

Publication date

September 1997

DOI

Abstract

At ambient temperatures, in acetonitrile, S,S-diphenylsulfimide reacted with CuCl2 (molar ratio 2:1) to give trans-[CuCl2{N(H)SPh2}(2)]; depending upon the crystallisation technique this can be isolated as either blue (perfect square-planar geometry) or green (pseudo-tetrahedral) crystals which do not interconvert in the solid state.</p

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Preparation and crystal structures of two forms of trans-[CuCl<sub>2</sub>{N(H)SPh<sub>2</sub>}<sub>2</sub>]; an unusual example of square planar/pseudo-tetrahedral isomerism in a neutral copper(II) complex

Abstract

Extracted data

Preparation and crystal structures of two forms of trans-[CuCl<sub>2</sub>{N(H)SPh<sub>2</sub>}<sub>2</sub>]; an unusual example of square planar/pseudo-tetrahedral isomerism in a neutral copper(II) complex

Abstract

Extracted data

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