The endeavor to enhance utility of organic molecular cages involves the evolution of them into higher-level chiral superstructures with self-similar, presenting a meaningful yet challenging. In this work, 2D tri-bladed propeller-shaped triphenylbenzene serves as building blocks to synthesize a racemic 3D tri-bladed propeller-shaped helical molecular cage. This cage, in turn, acts as a building block for a pair of higher-level 3D tri-bladed chiral helical molecular cages, featuring multilayer sandwich structures and displaying elegant characteristics with self-similarity in discrete superstructures at different levels. The evolutionary procession of higher-level cages reveals intramolecular self-shielding effects and exclusive chiral narciss...
: Spatial organization using confinement has been of great interest since the early ages of supramol...
A library of dendronized cyclotriveratrylene (CTV) crowns substituted with chiral, racemic, or achir...
Taking advantage of the dynamic covalent chemistry approach, four different cages were synthesized b...
The endeavor to enhance utility of organic molecular cages involves the evolution of them into highe...
We report the use of helicene with an intrinsic helical molecular structure to prepare covalent orga...
Chiral nanosized confinements play a major role for enantioselective recognition and reaction contro...
Chiral nanosized confinements play a major role for enantioselective recognition and reaction contro...
International audienceThe controlled preparation of chiral structures is a contemporary challenge fo...
Transfer of molecular chirality to supramolecular chirality at nanoscale and microscale by chemical ...
The bottom-up fabrication of surface hierarchical nanostructures is of great importance for the deve...
The formation of helical self-assembled fibres by a C-3 symmetric molecule incorporating three tetra...
Intertwining triple helical nanofibers with an overall handedness have been formed from self-assembl...
The control of solid state assembly for porous organic cages is more challenging than for extended f...
Bionic control over the assembly of achiral molecules into chiral supramolecular architectures is ch...
Bionic control over the assembly of achiral molecules into chiral supramolecular architectures is ch...
: Spatial organization using confinement has been of great interest since the early ages of supramol...
A library of dendronized cyclotriveratrylene (CTV) crowns substituted with chiral, racemic, or achir...
Taking advantage of the dynamic covalent chemistry approach, four different cages were synthesized b...
The endeavor to enhance utility of organic molecular cages involves the evolution of them into highe...
We report the use of helicene with an intrinsic helical molecular structure to prepare covalent orga...
Chiral nanosized confinements play a major role for enantioselective recognition and reaction contro...
Chiral nanosized confinements play a major role for enantioselective recognition and reaction contro...
International audienceThe controlled preparation of chiral structures is a contemporary challenge fo...
Transfer of molecular chirality to supramolecular chirality at nanoscale and microscale by chemical ...
The bottom-up fabrication of surface hierarchical nanostructures is of great importance for the deve...
The formation of helical self-assembled fibres by a C-3 symmetric molecule incorporating three tetra...
Intertwining triple helical nanofibers with an overall handedness have been formed from self-assembl...
The control of solid state assembly for porous organic cages is more challenging than for extended f...
Bionic control over the assembly of achiral molecules into chiral supramolecular architectures is ch...
Bionic control over the assembly of achiral molecules into chiral supramolecular architectures is ch...
: Spatial organization using confinement has been of great interest since the early ages of supramol...
A library of dendronized cyclotriveratrylene (CTV) crowns substituted with chiral, racemic, or achir...
Taking advantage of the dynamic covalent chemistry approach, four different cages were synthesized b...