Readily-available 1,1,1,2-tetrafluoroethane (Klea HFC-134a) can be converted, via a two-pot sequence into a range of Z--fluoroalkenoyl derivatives following addition reactions to aldehydes. Reaction adducts can be processed into enals and enones upon hydride reduction or Grignard reagent addition in high yield
A mild and versatile method for the construction of C–N bonds by the reaction of (2,2-difluorovinyl)...
Reported herein is the efficient synthesis of tetra- and tri-substituted ( Z )-fluoro- and ( Z )-chl...
Received: The date will be inserted once the manuscript is accepted. Abstract: Stereoselective synth...
Readily-available 1,1,1,2-tetrafluoroethane (Klea HFC-134a) can be converted, via a two-pot sequence...
Since the discovery of the fact that compounds bearing a vinylic fluoride moiety often exhibit remar...
International audienceThe selective synthesis of fluoroalkenoates is reported from a pyrimidinyl flu...
A regio- and stereoselective synthesis of fluorinated 1,4-enynes bearing an all-carbon quaternary ce...
Convenient access to homochiral fluoroalkenes is described via a Julia–Kocienski olefination reactio...
International audienceA highly stereospecific synthesis of (E)- or (Z)-alpha-fluoro-alpha,beta-unsat...
A general method for the synthesis of 1,1‐[18F]difluorinated alkenes from [18F]fluoride is reported....
A range of alkenyltrimethylsilanes are converted to alkenyl fluorides by reaction with one equivalen...
Convenient access to homochiral fluoroalkenes is described via a Julia-Kocienski olefination reactio...
Highly enantioselective cascade reactions for the synthesis of fluoroindanes and chromanols derivati...
(1E,3E)- and (1E,3Z)-4-fluoro-1,3-alkadienylboronates were stereoselectively prepared by the Heck-re...
International audienceHerein we report the hydrodefluorination reaction of trifluoromethylated alken...
A mild and versatile method for the construction of C–N bonds by the reaction of (2,2-difluorovinyl)...
Reported herein is the efficient synthesis of tetra- and tri-substituted ( Z )-fluoro- and ( Z )-chl...
Received: The date will be inserted once the manuscript is accepted. Abstract: Stereoselective synth...
Readily-available 1,1,1,2-tetrafluoroethane (Klea HFC-134a) can be converted, via a two-pot sequence...
Since the discovery of the fact that compounds bearing a vinylic fluoride moiety often exhibit remar...
International audienceThe selective synthesis of fluoroalkenoates is reported from a pyrimidinyl flu...
A regio- and stereoselective synthesis of fluorinated 1,4-enynes bearing an all-carbon quaternary ce...
Convenient access to homochiral fluoroalkenes is described via a Julia–Kocienski olefination reactio...
International audienceA highly stereospecific synthesis of (E)- or (Z)-alpha-fluoro-alpha,beta-unsat...
A general method for the synthesis of 1,1‐[18F]difluorinated alkenes from [18F]fluoride is reported....
A range of alkenyltrimethylsilanes are converted to alkenyl fluorides by reaction with one equivalen...
Convenient access to homochiral fluoroalkenes is described via a Julia-Kocienski olefination reactio...
Highly enantioselective cascade reactions for the synthesis of fluoroindanes and chromanols derivati...
(1E,3E)- and (1E,3Z)-4-fluoro-1,3-alkadienylboronates were stereoselectively prepared by the Heck-re...
International audienceHerein we report the hydrodefluorination reaction of trifluoromethylated alken...
A mild and versatile method for the construction of C–N bonds by the reaction of (2,2-difluorovinyl)...
Reported herein is the efficient synthesis of tetra- and tri-substituted ( Z )-fluoro- and ( Z )-chl...
Received: The date will be inserted once the manuscript is accepted. Abstract: Stereoselective synth...
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