Extension of the standard Molniya orbit using low-thrust propulsion is presented. These newly proposed, highly elliptical orbits are enabled by existing low-thrust propulsion technology, enabling new Earth Observation science and offering a new set of tools for mission design. In applying continuous low-thrust propulsion to the conventional Molniya orbit the critical inclination may be altered from the natural value of 63.4deg, to any inclination required to optimally fulfill the mission goals. Analytical expressions, validated using numerical methods, reveal the possibility of enabling a Molniya orbit inclined at 90deg to the equator. Fuel optimal low-thrust control profiles are then generated by the application of pseudo spectral numerica...