International audienceImpedance and vector network analyzer measurements are combined in order to measure frequency dependent conductivity and permittivity of two different saturated clays: montmorillonite and illite chlorite. In the low frequency range, the complex conductivity is determined over the 10 mHz to 45 kHz frequency range using a complex impedance analyzer with a 4-electrodes cell. In the high frequency range (50 MHz to 5 GHz), the complex permittivity is obtained from measured reflection factor of an open-ended probe. The ultrabroadband constitutive properties of the saturated clays were investigated in the temperature range 25 • C down to 0 • C. A mixture equation, based on a volume average approach, was applied to model the l...