Structural properties of magnetite under high pressure studied by Mossbauer spectroscopy

出版社版We have measured the Mossbauer spectra of magnetite (Fe3O4) under a pressure of up to 18 GPa at room temperature using nonenriched high-quality samples. An analysis of the observed Mossbauer spectra confirms that Fe3O4 does not undergo a magnetic or crystalline structural transition up to 18 GPa at room temperature. In the pressure dependences of the refined hyperfine interaction parameters, however, small but distinct anomalies are found at 7.0 GPa in the center shifts of two crystallographically nonequivalent Fe sites, which are caused by the discontinuous decrease of an oxygen internal coordinate in the cubic inverse spinel structure. We believe that the pressure-induced discontinuous change of the Fe-O bond length is related to the absence of a metal-insulator transition above 7.5 GPa