Amine-modified polyionic liquid supports enhance the efficacy of PdNPs for the catalytic hydrogenation of CO₂ to formate
- Paterson, R.
- Fahy, L.E.
- Arca, E.
- Dixon, C.
- Wills, C.Y.
- Yan, H.
- Griffiths, A.
- Collins, S.M.
- Wu, K.
- Bourne, R.A.
- Chamberlain, T.W.
- Knight, J.G.
- Doherty, S.
DOIAbstract
Palladium nanoparticles stabilised by aniline modified polymer immobilised ionic liquid is a remarkably active catalyst for the hydrogenation of CO₂ to formate; the initial TOF of 500 h⁻¹ is markedly higher than either unmodified catalyst or its benzylamine and N,N-dimethylaniline modified counterparts and is among the highest to be reported for a PdNP-based catalyst
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