Elasticity of plagioclase feldspars

AbstractElastic properties are reported for eight plagioclase feldspars that span compositions from albite (NaSi3AlO8) to anorthite (CaSi2Al2O8). Surface acoustic wave velocities measured using Impulsive Stimulated Light Scattering and compliance sums from high‐pressure X‐ray compression studies accurately determine all 21 components of the elasticity tensor for these triclinic minerals. The overall pattern of elasticity and the changes in individual elastic components with composition can be rationalized on the basis of the evolution of crystal structures and chemistry across this solid‐solution join. All plagioclase feldspars have high elastic anisotropy; a* (the direction perpendicular to the b and c axes) is the softest direction by a factor of 3 in albite. From albite to anorthite the stiffness of this direction undergoes the greatest change, increasing twofold. Small discontinuities in the elastic components, inferred to occur between the three plagioclase phases with distinct symmetry ( , , and ), appear consistent with the nature of the underlying conformation of the framework‐linked tetrahedra and the associated structural changes. Measured body wave velocities of plagioclase‐rich rocks, reported over the last five decades, are consistent with calculated Hill‐averaged velocities using the current moduli. This confirms long‐standing speculation that previously reported elastic moduli for plagioclase feldspars are systematically in error. The current results provide greater assurance that the seismic structure of the middle and lower crusts can be accurately estimated on the basis of specified mineral modes, chemistry, and fabric