While there have been a significant number of publications in the field of frustrated Lewis pair chemistry, only a fraction employ aluminum-based Lewis acids. The research presented herein expands the scope of Lewis acids to include novel aluminum-based compounds. N-heterocyclic carbene-stabilized three-coordinate aluminum cations were synthesized from the NHC-AlR3 adduct by abstraction of an R substituent from aluminum. These compounds were crystallographically characterized and exhibited solvent-dependent reactivity. Hydrogenation catalysis and radical reactivity were also explored experimentally and computationally.M.Sc
The main focus of this thesis is to explore structural modifications of one of our published achiral...
A series of dichloroaluminum carboxylates [Cl<sub>2</sub>Al(O<sub>2</sub>CR)]<sub>2</sub> (were R =...
Frustrated Lewis pairs (FLP) have been introduced as an alternative to transition metal catalyst. Si...
While there have been a significant number of publications in the field of frustrated Lewis pair che...
While hundreds of papers have been published on frustrated Lewis pairs (FLPs) – the combination of b...
Trivalent aluminium compounds are well known for their reactivity as Lewis acids/electrophiles, a fe...
The reactivity of aluminium compounds is dominated by their electron deficiency and consequent elect...
Both fields, hydrogen storage and Frustrated Lewis Pair chemistry, have evolved tremendously in the ...
Since the discovery of frustrated Lewis pairs (FLPs), a pair of sterically encumbered Lewis acids an...
Aluminum(III) is inherently electron deficient and therefore acts as a prototypical Lewis acid. Conv...
Trivalent aluminium compounds are well known for their reactivity as Lewis acids/electrophiles, a fe...
The synthesis and full characterization of a new heteroleptic <i>N</i>-heterocyclic carbene (NHC)–ph...
In this study the reactivity of the compound dimethyl [2-(N,N- dmiemylethylen)cyclopentadienyl)]Al(I...
In search of stable, yet reactive aluminum Lewis acids, we have isolated an organoaluminum cation, (...
Bulky aluminum Lewis acids such as MAD and MABR are introduced as new efficient catalysts in substoi...
The main focus of this thesis is to explore structural modifications of one of our published achiral...
A series of dichloroaluminum carboxylates [Cl<sub>2</sub>Al(O<sub>2</sub>CR)]<sub>2</sub> (were R =...
Frustrated Lewis pairs (FLP) have been introduced as an alternative to transition metal catalyst. Si...
While there have been a significant number of publications in the field of frustrated Lewis pair che...
While hundreds of papers have been published on frustrated Lewis pairs (FLPs) – the combination of b...
Trivalent aluminium compounds are well known for their reactivity as Lewis acids/electrophiles, a fe...
The reactivity of aluminium compounds is dominated by their electron deficiency and consequent elect...
Both fields, hydrogen storage and Frustrated Lewis Pair chemistry, have evolved tremendously in the ...
Since the discovery of frustrated Lewis pairs (FLPs), a pair of sterically encumbered Lewis acids an...
Aluminum(III) is inherently electron deficient and therefore acts as a prototypical Lewis acid. Conv...
Trivalent aluminium compounds are well known for their reactivity as Lewis acids/electrophiles, a fe...
The synthesis and full characterization of a new heteroleptic <i>N</i>-heterocyclic carbene (NHC)–ph...
In this study the reactivity of the compound dimethyl [2-(N,N- dmiemylethylen)cyclopentadienyl)]Al(I...
In search of stable, yet reactive aluminum Lewis acids, we have isolated an organoaluminum cation, (...
Bulky aluminum Lewis acids such as MAD and MABR are introduced as new efficient catalysts in substoi...
The main focus of this thesis is to explore structural modifications of one of our published achiral...
A series of dichloroaluminum carboxylates [Cl<sub>2</sub>Al(O<sub>2</sub>CR)]<sub>2</sub> (were R =...
Frustrated Lewis pairs (FLP) have been introduced as an alternative to transition metal catalyst. Si...
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