Probing Excitonic Dark States in Single-layer Tungsten Disulfide

The emergence of graphene optoelectronics has stimulated the development of near-transparent two-dimensional semiconductor materials. Much attention is focusing on the potentially extremely versatile transition metal dichalcogenides, such as molybdenum disulphide and tungsten disulphide, as components for ultrathin electronic devices. The physical origins of the unusually strong lightmatter interactions in these materials remain unclear. An active topic in this area is how excitons (electron-hole pairs generated by light) behave in these low-dimensional systems. Here Xiang Zhang and colleagues report the discovery of a series of two-dimensional excitonic dark states in monolayer tungsten disulphide that have strong binding energy and an energy dependence on orbital momentum that significantly deviates from conventional (3D) behaviour. The findings open new avenues for fundamental research and opportunities to design devices such as photodetectors and photovoltaic cells