Fig. 9. (a) Spectral variations of the trans-chalcone at pH = 5.0 in methanol:water (1:1) at 45 °C, [Ct] = 5.0 × 10−5 M. The same behaviour is observed in the pH range 1Published as part of Alejo-Armijo, A., Mendoza, Johan, Parola, A. Jorge & Pina, Fernando, 2020, Chemical evolution of the colour systems generated by riccionidin A, 3-deoxyanthocyanidins and anthocyanins, pp. 1-11 in Phytochemistry (112339) 174 on page 5, DOI: 10.1016/j.phytochem.2020.112339, http://zenodo.org/record/829467
Fig. 3. (a) Representation of the rate constants versus pH of the second step for Oenin 2.5 × 10−5 M...
Fig. 10. Proposed chemical structures for peaks 1, 2, 5 and 6 detected by HPLC-MS and possible mecha...
Fig. 1. Anthocyanins, 3-deoxyanthocyanins, auronidin and their respective aglycones together with tw...
Fig. 7. (a) Spectral variations during the synthesis of riccionidin A; (b) Spectral variations of tr...
Fig. 11. (a) Chromatographic profile of trans-chalcone (4) in methanol:water 1:1 (0.5 mM, pH = 7.1) ...
Fig. 13. pH dependent spectral modifications of riccionidin A, [AH+] = 3.3 × 10−5 M upon pH jumps fr...
Fig. 14. (a) Spectral variations of riccionidin A taken immediately after direct pH jumps from the f...
Fig. 12. (a) Irradiation of trans-chalcone at 366 nm in acetonitrile (with a drop of TFA); [Ct] = 3....
Fig. 5. (a) pH 1.0, [Ct] = 2.5 × 10−5 M; the curves correspond to the irradiation times 0.0.5, 1, 2,...
Fig. 4. (a) Bell-shaped curve of the reaction towards the equilibrium versus pH of luteolinidin 2.5 ...
Fig. 8. Proposed protonation sequence for the trans-chalcone species. The numeration of the flavyliu...
Fig. 17. Chromatographic profile (at 300 nm) of flavylium salt (compound 8) solution (methanol:water...
Alejo-Armijo, A., Mendoza, Johan, Parola, A. Jorge, Pina, Fernando (2020): Chemical evolution of the...
Fig. 16. Kinetics of the direct pH jumps from flavylium cation at pH = 1.0 at room temperature, [AH+...
Fig. 15. Top: proposed deprotonation sequence for flavylium cation of riccionidin A; bottom: colour ...
Fig. 3. (a) Representation of the rate constants versus pH of the second step for Oenin 2.5 × 10−5 M...
Fig. 10. Proposed chemical structures for peaks 1, 2, 5 and 6 detected by HPLC-MS and possible mecha...
Fig. 1. Anthocyanins, 3-deoxyanthocyanins, auronidin and their respective aglycones together with tw...
Fig. 7. (a) Spectral variations during the synthesis of riccionidin A; (b) Spectral variations of tr...
Fig. 11. (a) Chromatographic profile of trans-chalcone (4) in methanol:water 1:1 (0.5 mM, pH = 7.1) ...
Fig. 13. pH dependent spectral modifications of riccionidin A, [AH+] = 3.3 × 10−5 M upon pH jumps fr...
Fig. 14. (a) Spectral variations of riccionidin A taken immediately after direct pH jumps from the f...
Fig. 12. (a) Irradiation of trans-chalcone at 366 nm in acetonitrile (with a drop of TFA); [Ct] = 3....
Fig. 5. (a) pH 1.0, [Ct] = 2.5 × 10−5 M; the curves correspond to the irradiation times 0.0.5, 1, 2,...
Fig. 4. (a) Bell-shaped curve of the reaction towards the equilibrium versus pH of luteolinidin 2.5 ...
Fig. 8. Proposed protonation sequence for the trans-chalcone species. The numeration of the flavyliu...
Fig. 17. Chromatographic profile (at 300 nm) of flavylium salt (compound 8) solution (methanol:water...
Alejo-Armijo, A., Mendoza, Johan, Parola, A. Jorge, Pina, Fernando (2020): Chemical evolution of the...
Fig. 16. Kinetics of the direct pH jumps from flavylium cation at pH = 1.0 at room temperature, [AH+...
Fig. 15. Top: proposed deprotonation sequence for flavylium cation of riccionidin A; bottom: colour ...
Fig. 3. (a) Representation of the rate constants versus pH of the second step for Oenin 2.5 × 10−5 M...
Fig. 10. Proposed chemical structures for peaks 1, 2, 5 and 6 detected by HPLC-MS and possible mecha...
Fig. 1. Anthocyanins, 3-deoxyanthocyanins, auronidin and their respective aglycones together with tw...