Fig. 4. 1H NMR spectra (400 MHz, D O) of a crab apple extract fraction (I) and sucrose (II). The circled signal was consistent with the anomeric proton of a β-AAG.Published as part of Richardson, Alistair T., Cho, Jung, McGhie, Tony K., Larsen, David S., Schaffer, Robert J., Espley, Richard V. & Perry, Nigel B., 2020, Discovery of a stable vitamin C glycoside in crab apples (Malus sylvestris), pp. 1-9 in Phytochemistry (112297) 173 on page 4, DOI: 10.1016/j.phytochem.2020.112297, http://zenodo.org/record/829446
NMR is a valuable tool for metabolomics due to its short analysis time and reproducibility. However,...
International audienceAcerola (Malpighia emarginata D.C.) is an exotic fruit with high agro-industri...
Apple scab, caused by the fungus Venturia inaequalis, is the most serious disease of the apple world...
Fig. 6. 1 H NMR spectra of β-glucoside 2 in D O (400 MHz) demonstrating the effect of pH on proton r...
Fig. 8. The downfield regions of the 1H NMR spectra for acetylated ascorbyl glycosides (structures i...
Richardson, Alistair T., Cho, Jung, McGhie, Tony K., Larsen, David S., Schaffer, Robert J., Espley, ...
Fig. 9. LC-MS (Instrument B, method II) extracted ion chromatograms for m/z 655, [M + Na]+, of acety...
Fig. 3. LC-MS chromatograms (Instrument B, method I) of crab apple extract, commercial 2-O-α-D-gluco...
Fig. 7. Acetylation of 2 under basic conditions gave the unsaturated glycoside 8, but acidic conditi...
Fig. 5. Synthetic route to AAGs 2 and 2a. I. Acetone, CH3COCl, overnight, room temp. (RT), II. PhCH2...
Fig. 2. Left: PCA (Pareto scaling with 95% confidence interval) of the LC-MS analyses of extracts fr...
Fig. 1. Structures of AA (1) and the only known naturally occurring derivatives in plants, 2-O-β-D-g...
The primary aim of the research described in this thesis was to investigate an ascorbyl glycoside te...
The metabolite profile of ten traditional apple cultivars grown in the Piedmont region (Italy) was s...
Apple scab, caused by the fungus Venturia inaequalis, is the most serious disease of the apple world...
NMR is a valuable tool for metabolomics due to its short analysis time and reproducibility. However,...
International audienceAcerola (Malpighia emarginata D.C.) is an exotic fruit with high agro-industri...
Apple scab, caused by the fungus Venturia inaequalis, is the most serious disease of the apple world...
Fig. 6. 1 H NMR spectra of β-glucoside 2 in D O (400 MHz) demonstrating the effect of pH on proton r...
Fig. 8. The downfield regions of the 1H NMR spectra for acetylated ascorbyl glycosides (structures i...
Richardson, Alistair T., Cho, Jung, McGhie, Tony K., Larsen, David S., Schaffer, Robert J., Espley, ...
Fig. 9. LC-MS (Instrument B, method II) extracted ion chromatograms for m/z 655, [M + Na]+, of acety...
Fig. 3. LC-MS chromatograms (Instrument B, method I) of crab apple extract, commercial 2-O-α-D-gluco...
Fig. 7. Acetylation of 2 under basic conditions gave the unsaturated glycoside 8, but acidic conditi...
Fig. 5. Synthetic route to AAGs 2 and 2a. I. Acetone, CH3COCl, overnight, room temp. (RT), II. PhCH2...
Fig. 2. Left: PCA (Pareto scaling with 95% confidence interval) of the LC-MS analyses of extracts fr...
Fig. 1. Structures of AA (1) and the only known naturally occurring derivatives in plants, 2-O-β-D-g...
The primary aim of the research described in this thesis was to investigate an ascorbyl glycoside te...
The metabolite profile of ten traditional apple cultivars grown in the Piedmont region (Italy) was s...
Apple scab, caused by the fungus Venturia inaequalis, is the most serious disease of the apple world...
NMR is a valuable tool for metabolomics due to its short analysis time and reproducibility. However,...
International audienceAcerola (Malpighia emarginata D.C.) is an exotic fruit with high agro-industri...
Apple scab, caused by the fungus Venturia inaequalis, is the most serious disease of the apple world...