Chlorine Derivatives of Mixed Amine Molybdenum Tricarbonyls

Department of Chemistry, S. N. Science Campus, Mahendra Nagar, Mahakali Zone, Nepal Manuscript received 5 May 1978, revised 8 June 1979, accepted 26 July 1980 [(L- L)(Am) Mo(CO)3CI]CI3 derivatives of Mo(II) and non-ionic (L- L)(Am)MoCI4 complexes of Mo(IV) have been prepared by chlorine oxidation of (L- L (Am)Mo(CO)3 (where,L-L=o-phen or 2,2'-bipy and Am=monodentate amines). Structures of the complexes have been proposed on the basis of elemental analysis, magnetic moment, molar conductance and infrared spectra