The properties of roller compacted concrete (RCC) with high volume low quality fly ash are investigated, including strength, elastic modulus, impermeability and frost resistance, meanwhile the microstructure of the cement paste containing low quality fly ash and ground low quality fly ash are also studied by using X-ray diffraction (XRD), scanning electron microscopy (SEM), thermogravimetry-differential thermal analysis (TG-DTA) and Mercury Intrusion Porosimetry (MIP). The results indicate that the properties of RCC containing 60 % or more ground fly ash meet the design requirement. When incorporated with high volume (60 %) ground fly ash, the effect of the pozzolanic reaction was observed at 7 days by consumption of portlandite. At the hyd...