Department of Chemistry, Sola pur University, Solapur-413 255, Maharashtra, India Fax: 91-0217-2744770 Manuscript received 7 December 2006, accepted 27 February 2007 The palladium catalyzed acyldemetallation reactions of methyl mercury iodide provide a mild, selective and general method for the construction of new C-C bond i.e. for the synthesis of unsymmetrical ketone. The rection proceeds in acetone, in the presence of a nucleophilic catalyst (iodide ion), at room temperature. The catalytic cycle involved in the reaction consists of a sequence of oxidative addition, transmetallation and reductive elimination steps. The role played by the iodide ion as a nucleophilic catalyst is discussed
A palladium-based catalytic system is highly active in the synthesis of γ-keto acids of type ArCOCH2...
A commercially available palladium complex bearing a N-heterocyclic carbene (NHC) was used in gram-s...
Shivraj College of Science, Gadhinglaj-416 502 Manuscript received 12 August 1993, accepted 16 Novem...
Department of Chemistry, Solapur University, Solapur-413 255, Maharashtra, India Fax : 91-217-27447...
The first part of this thesis discusses an unprecedented acylation of allylic mercurials by acyl chl...
Recent trends in research have gained an orientation towards developing efficient strategies using i...
Abstract: The application of palladium catalyzed reactions, such as cross-coupling, Heck arylation, ...
Recent trends in research have gained an orientation toward developing efficient strategies using in...
To grasp the essence of organic chemistry, quickly comes to one’s mind is the C–C bond forming reac...
A palladium-based catalytic system is highly active in the synthesis of γ-keto acids of type ArCOCH2...
A surprisingly practical Pd(OAc)(2) or Pd(TFA)(2)-catalyzed reductive Heck reaction between aryl iod...
We describe a new approach to acid chloride synthesis via the palladium-catalyzed carbonylation of a...
Alkyl aryl ketones were synthesized by the carbonylative cross-coupling reaction of alkyl iodides an...
Aryl and alkenylpalladium compounds generated by oxidative addition of a palladium(0) catalyst to th...
actions of functionalized alkenyl halides and a variety of Grignard reagents, including those bearin...
A palladium-based catalytic system is highly active in the synthesis of γ-keto acids of type ArCOCH2...
A commercially available palladium complex bearing a N-heterocyclic carbene (NHC) was used in gram-s...
Shivraj College of Science, Gadhinglaj-416 502 Manuscript received 12 August 1993, accepted 16 Novem...
Department of Chemistry, Solapur University, Solapur-413 255, Maharashtra, India Fax : 91-217-27447...
The first part of this thesis discusses an unprecedented acylation of allylic mercurials by acyl chl...
Recent trends in research have gained an orientation towards developing efficient strategies using i...
Abstract: The application of palladium catalyzed reactions, such as cross-coupling, Heck arylation, ...
Recent trends in research have gained an orientation toward developing efficient strategies using in...
To grasp the essence of organic chemistry, quickly comes to one’s mind is the C–C bond forming reac...
A palladium-based catalytic system is highly active in the synthesis of γ-keto acids of type ArCOCH2...
A surprisingly practical Pd(OAc)(2) or Pd(TFA)(2)-catalyzed reductive Heck reaction between aryl iod...
We describe a new approach to acid chloride synthesis via the palladium-catalyzed carbonylation of a...
Alkyl aryl ketones were synthesized by the carbonylative cross-coupling reaction of alkyl iodides an...
Aryl and alkenylpalladium compounds generated by oxidative addition of a palladium(0) catalyst to th...
actions of functionalized alkenyl halides and a variety of Grignard reagents, including those bearin...
A palladium-based catalytic system is highly active in the synthesis of γ-keto acids of type ArCOCH2...
A commercially available palladium complex bearing a N-heterocyclic carbene (NHC) was used in gram-s...
Shivraj College of Science, Gadhinglaj-416 502 Manuscript received 12 August 1993, accepted 16 Novem...