Intramolecular acylation of lactones to yield cyclopentenones in the presence of polyphosphoric acid has been extended to δ-lactones. Based on this, convenient, possibly general, routes to bicyclo. [0 : 3: 3]--octane and bicyclo-[o :3 :4]-nonane systems have been described. The reaction has been discussed from the mechanistic point of view
Version of record online: July 14, 2022Structurally unique natural products pose biosynthetic puzzle...
The objective of this study was to explore intramolecular ketene cycloadditions with the anticipated...
THESIS 7151The research undertaken in the present study focuses on the synthesis of lactones via the...
It has been demonstrated that the intramolecular acylation of suitably constituted \(\gamma\)-lacton...
Polyphosphoric acid has been shown to be a useful reagent for the one-step synthesis of certain cycl...
Aromatic hydrocarbons, phenol ethers and alicyclic olefines can be conveniently acylated by various ...
Both pyrophosphoryl chloride and phosphorus oxychloride react with aryl aliphatic acids to form mixe...
The <i>n</i>-Bu<sub>3</sub>P organocatalyzed reaction of cycloalkanones, i.e., cyclopentanones or 1,...
Acetylation of cycloheptene in polyphosphoric acid at ≈65± is shown to be accompanied by ring-contra...
The efficacy of a new acid-catalyzed intramolecular C-alkylation has been demonstrated by the synthe...
International audienceA new rapid synthesis of γ-lactones, cis fused with a cyclopentenic ring by th...
The polyphosphoric acid induced intramolecular acylation of lactones has been applied to the synthes...
The combination of palladium acetate and 1,4-bis(diphenylphosphino)butane (dppb) proved once again t...
The polyphosphoric acid induced intramolecular acylation of lactones has been applied to the synthes...
The cyclopropyl carbinols 8 and 9 obtained by either borohydride reduction (or Grignard addition) of...
Version of record online: July 14, 2022Structurally unique natural products pose biosynthetic puzzle...
The objective of this study was to explore intramolecular ketene cycloadditions with the anticipated...
THESIS 7151The research undertaken in the present study focuses on the synthesis of lactones via the...
It has been demonstrated that the intramolecular acylation of suitably constituted \(\gamma\)-lacton...
Polyphosphoric acid has been shown to be a useful reagent for the one-step synthesis of certain cycl...
Aromatic hydrocarbons, phenol ethers and alicyclic olefines can be conveniently acylated by various ...
Both pyrophosphoryl chloride and phosphorus oxychloride react with aryl aliphatic acids to form mixe...
The <i>n</i>-Bu<sub>3</sub>P organocatalyzed reaction of cycloalkanones, i.e., cyclopentanones or 1,...
Acetylation of cycloheptene in polyphosphoric acid at ≈65± is shown to be accompanied by ring-contra...
The efficacy of a new acid-catalyzed intramolecular C-alkylation has been demonstrated by the synthe...
International audienceA new rapid synthesis of γ-lactones, cis fused with a cyclopentenic ring by th...
The polyphosphoric acid induced intramolecular acylation of lactones has been applied to the synthes...
The combination of palladium acetate and 1,4-bis(diphenylphosphino)butane (dppb) proved once again t...
The polyphosphoric acid induced intramolecular acylation of lactones has been applied to the synthes...
The cyclopropyl carbinols 8 and 9 obtained by either borohydride reduction (or Grignard addition) of...
Version of record online: July 14, 2022Structurally unique natural products pose biosynthetic puzzle...
The objective of this study was to explore intramolecular ketene cycloadditions with the anticipated...
THESIS 7151The research undertaken in the present study focuses on the synthesis of lactones via the...