Supplemental tables for a study of the seasonal Impacts of the Physical Environment on Biogeochemical Cycles in Arctic Lakes of the Mackenzie River Delta

submitted abstract We conducted two- and six-year-long deployments of continuous water samplers (OsmoSamplers) and sensors (Temperature, pressure, light level, dissolved oxygen (DO) and conductivity) in nine lakes within the mid- to outer-delta region of the Mackenzie River and documented biogeochemical fluctuations (Mn, Fe, sulfate, and DO), defined physical processes that that drive such fluctuations, and constrained the impact of lake solutes on annual riverine fluxes. Five lakes were in the mid-delta region near Inuvik, NT, two lakes were in the outer delta, and two lakes were on the Arctic coastal plain and were not impacted by the Mackenzie River. In general, temperature minima occurred in September/October, indicative of ice formation, and distinct hydrostatic pressure (water level) anomalies occurred in May/June associated with ice breakup, lasting for days to months and impacting lake levels up to 4.2 m higher than “normal”. Such anomalies coincide with a dramatic change in solute concentrations. Systematic changes in solute concentrations indicate redox-driven biogeochemical reactions, salt exclusion during ice formation, and continuous to sporadic exchange of river water. Redox reactions were regulated by DO inputs stemming from atmospheric, photosynthetic, and riverine sources. During ice-covered periods dissolved sulfate may be conservative but was generally removed. Manganese and iron concentrations showed phases of production and removal during ice-covered periods, but both were produced overall. Calculated solute fluxes from lake waters alone to the Arctic Ocean may only impact yearly riverine fluxes for solutes that exceed ten times the river concentration prior to ice breakup (e.g., Mn and Fe).Three Key points 140 maximum characters with spaces) 1. Continuous water samplers and sensors constrain physical forcing and oxygen inputs that affect biogeochemical processes in Arctic lakes. 2. Once dissolved oxygen is removed, dissolved Mn then Fe are released to lake waters; eventually sulfate removal occurs in most lakes. 3. Lake solutes (Mn and Fe) can affect yearly riverine fluxes if increases in concentration prior to spring floods are greater than 10 fold