Impedance spectroscopy analysis of a thermo-electrochemical cell under operating conditions
- Castro-Ruiz, Sergio
- García-Cañadas, Jorge
DOIAbstract
Low-grade (<200°C) heat is an abundant and available energy not generally exploited. In this regard, the so-called thermo-electrochemical cells have become a valid opportunity to harvest this ubiquitous source of heat. They are capable to convert heat into electricity by means of the temperature-redox potential dependency of a redox couple. In fact, they present Seebeck coefficient values in order of mV/K, much higher than solid-state thermoelectrics. In this work, a system formed by two Pt electrodes in contact with a 0.4 M ferro/ferricyanide aqueous solution has been studied by means of impedance spectroscopy under operating conditions (ΔT=40 K). The main processes which govern the performance of the system have been identified, which lea...
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