The Hubble diagram continues to remain one of the most important graphical representations in the realm of astronomy and cosmology right from its genesis that depicts the velocity-distance relation for the receding large-scale structures within the Universe; it is the diagram that helps us to understand the Universe’s expansion. In this paper I introduce the molecular expansion model in order to explain the expansion of the Universe. The molecular expansion model considers the large-scale structures as gas molecules undergoing free expansion into the vacuum. Large-scale structures being ensemble of atoms must behave like molecules possessing finite amount of energy. Since metric expansion of space cannot be tested practically and can only b...