Broad Scope Aminocyclization of Enynes with Cationic JohnPhos-Gold(I) Complex as the Catalyst
- R. Miller, J. Carreras, M. E. Muratore,
- Gaydou, M
- Camponovo, F
- Echavarren, A.M.
- Miller, R
- Carreras, J
- Muratore, M.E.
Publication date
March 2016
DOIAbstract
A practical aminocyclization of 1,6-enynes with a wide variety of substituted anilines, including N-alkyl anilines, has been achived by using cationic [JohnPhosAu(MeCN)]SbF6 as a general purpose catalyst. The resulting adducts can be easily converted into polycyclic compounds by palladium- and gold-catalyzed reactions
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