This dataset refers to the article: "Rock magnetic fingerprint of Mt. Etna volcanic ash" by the same authors, published in Geophysical Journal International, https://doi.org/10.1093/gji/ggac213. A detailed rock magnetic study was conducted on ash samples collected from different products erupted during explosive activity of Mount Etna, Italy, in order to test the use of magnetic properties as discriminating factors among them, and their explosive character in particular. Samples include tephra emplaced during the last 18 ka: the benmoreitic Plinian eruptions of the Pleistocene Ellittico activity from marine core ET97-70 (Ionian Sea) and the basaltic Holocene FG eruption (122 BC), the Strombolian/Phreatomagmatic/sub-Plinian eruptions (namel...