Crystal structure of catena-poly[[gold(I)-μ-cyanido-[di­aqua­bis­­(2-phenyl­pyrazine)­iron(II)]-μ-cyanido] dicyanidogold(I)]

In the title polymeric complex, {[Fe(CN)2(C10H8N2)2(H2O)2][Au(CN)2]}n, the FeII ion, which is located on a twofold rotation axis, has a slightly distorted FeN4O2 octa­hedral geometry. It is coordinated by two phenyl­pyrazine mol­ecules, two water mol­ecules and two di­cyano­aurate anions, the Au atom also being located on a second twofold rotation axis. In the crystal, the coordinated di­cyano­aurate anions bridge the FeII ions to form polymeric chains propagating along the b-axis direction. In the crystal, the chains are linked by Owater—H⋯Ndi­cyano­aurate anions hydrogen bonds and aurophillic inter­actions [Au⋯Au = 3.5661 (3) Å], forming layers parallel to the bc plane. The layers are linked by offset π–π stacking inter­actions [inter­centroid distance = 3.643 (3) Å], forming a supra­molecular metal–organic framework