We report an investigation into the regioselectivity of the aromatic Claisen rearrangement within a novel asymmetric substrate that possesses an internal base meta to the aryl allyl ether position. We utilize various migratory aryl allyl ethers and aryl propargyl ethers to study how steric bulk influences the regioselectivity. Our results show that steric bulk does influence the regioselectivity of the aromatic Claisen rearrangement
The Claisen rearrangement is a carbon-carbon bond-forming, pericyclic reaction of fundamental import...
In the first part of this thesis, the competition between the (3,3) Claisen rearrangement and the (2...
The Claisen rearrangement of allyl phenyl ether, allyl phenylamine, and allyl phenyl thioether, toge...
Theoretical calculations and the isomeric product composition for a series of eight meta-substituted...
Theoretical calculations and the isomeric product composition for a series of eight meta-substituted...
Recently we reported the aromatic Claisen rearrangements of benzyl ketene acetals, which form one of...
The regioselectivity of the Claisen rearrangement of allylindanyl and allyltetrahydronaphthalenyl et...
The regioselectivity of the Claisen rearrangement of allylindanyl and allyltetrahydronaphthalenyl et...
239 p.Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 1985.A new variant of the Claisen ...
A summary of research conducted since September 2007 at the University of Toronto in the laboratory ...
A summary of research conducted since September 2007 at the University of Toronto in the laboratory ...
It is known that phenyl alkyl ethers substitute in the phenyl radical less easily than phenol; never...
Iridium(I)-catalyzed olefin isomerization in bis(allyl) ethers is integrated into a generally applic...
Three allylic type alcohols were rearranged in sulfuric acid (l, 10 and 50%) at 25 and 100C and thei...
The development of an enantioselective catalytic Claisen rearrangement remains an important yet elu...
The Claisen rearrangement is a carbon-carbon bond-forming, pericyclic reaction of fundamental import...
In the first part of this thesis, the competition between the (3,3) Claisen rearrangement and the (2...
The Claisen rearrangement of allyl phenyl ether, allyl phenylamine, and allyl phenyl thioether, toge...
Theoretical calculations and the isomeric product composition for a series of eight meta-substituted...
Theoretical calculations and the isomeric product composition for a series of eight meta-substituted...
Recently we reported the aromatic Claisen rearrangements of benzyl ketene acetals, which form one of...
The regioselectivity of the Claisen rearrangement of allylindanyl and allyltetrahydronaphthalenyl et...
The regioselectivity of the Claisen rearrangement of allylindanyl and allyltetrahydronaphthalenyl et...
239 p.Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 1985.A new variant of the Claisen ...
A summary of research conducted since September 2007 at the University of Toronto in the laboratory ...
A summary of research conducted since September 2007 at the University of Toronto in the laboratory ...
It is known that phenyl alkyl ethers substitute in the phenyl radical less easily than phenol; never...
Iridium(I)-catalyzed olefin isomerization in bis(allyl) ethers is integrated into a generally applic...
Three allylic type alcohols were rearranged in sulfuric acid (l, 10 and 50%) at 25 and 100C and thei...
The development of an enantioselective catalytic Claisen rearrangement remains an important yet elu...
The Claisen rearrangement is a carbon-carbon bond-forming, pericyclic reaction of fundamental import...
In the first part of this thesis, the competition between the (3,3) Claisen rearrangement and the (2...
The Claisen rearrangement of allyl phenyl ether, allyl phenylamine, and allyl phenyl thioether, toge...