In this work, the photolysis of ferrioxalate complexes attended to the photoreduction of hexavalent chromium has been studied kinetically and mechanistically in aqueous solutions, under UV/Visible irradiation . The results showed, that the iron(III) undergoes rapid photoreduction to iron(II), occompanied by oxidative degradation of oxalic ligands to carbon dioxide . Photochemically generated is readily reoxidized to by the present in the deaerated - system, thus the is reduced to at last. In addition, kinetics of the overall occurring photoreaction has been discussed, and its probable mechanism has been suggested under the experimental conditions employed.
Stable organic species produced on irradiation of Suwannee River Fulvic Acid (SRFA) are shown to be ...
Fe(III)–oxalate complexes are likely abundant in clouds, fogs and aerosol water. They are photoreac...
Department of Chemistry, University of Rajasthan, Jaipur-302 004, India Manuscript received 7 Septem...
Iron(III) oxalate, Fe<sup>3+</sup>(C<sub>2</sub>O<sub>4</sub>)<sub>3</sub><sup>3–</sup>, is a photo...
Iron(III) oxalate, Fe3+(C2O4)33-, is a photoactive metal organic complex found in natural systems an...
The kinetics of photocatalytic degradation of Reactive Brilliant blue KN-R, Acid Scarlet GR and Reac...
International audienceIn this work, the photo reactivity of ferric oxalate (Fe(III)-Ox) complex in a...
The mechanisms of photo-catalytic reduction of Cr(VI) were investigated in acidic solutions with and...
The roles of chromium species on photochemical cycling of iron and mineralization of polycarboxylate...
Irradiation of the [Cr(C2O4)3]3 complex or the chromate(VI)–oxalate mixture, or the ternary system c...
Photocatalytic reduction of hexavalent chromium (Cr(VI)) in ferric-tartrate system under irradiation...
The photoreactions between Fe(III)/Fe(II) and low-molecular-weight organic matter (LMWOM) under sola...
The photo-ferrioxalate system (PFS), [Fe(III)(C2O4)]3–, more than an exact chemical actinometer, has...
In this paper, the photochemical reduction process of Hg (II) in aqueous solution containing ferric ...
Stable organic species produced on irradiation of Suwannee River Fulvic Acid (SRFA) are shown to be ...
Stable organic species produced on irradiation of Suwannee River Fulvic Acid (SRFA) are shown to be ...
Fe(III)–oxalate complexes are likely abundant in clouds, fogs and aerosol water. They are photoreac...
Department of Chemistry, University of Rajasthan, Jaipur-302 004, India Manuscript received 7 Septem...
Iron(III) oxalate, Fe<sup>3+</sup>(C<sub>2</sub>O<sub>4</sub>)<sub>3</sub><sup>3–</sup>, is a photo...
Iron(III) oxalate, Fe3+(C2O4)33-, is a photoactive metal organic complex found in natural systems an...
The kinetics of photocatalytic degradation of Reactive Brilliant blue KN-R, Acid Scarlet GR and Reac...
International audienceIn this work, the photo reactivity of ferric oxalate (Fe(III)-Ox) complex in a...
The mechanisms of photo-catalytic reduction of Cr(VI) were investigated in acidic solutions with and...
The roles of chromium species on photochemical cycling of iron and mineralization of polycarboxylate...
Irradiation of the [Cr(C2O4)3]3 complex or the chromate(VI)–oxalate mixture, or the ternary system c...
Photocatalytic reduction of hexavalent chromium (Cr(VI)) in ferric-tartrate system under irradiation...
The photoreactions between Fe(III)/Fe(II) and low-molecular-weight organic matter (LMWOM) under sola...
The photo-ferrioxalate system (PFS), [Fe(III)(C2O4)]3–, more than an exact chemical actinometer, has...
In this paper, the photochemical reduction process of Hg (II) in aqueous solution containing ferric ...
Stable organic species produced on irradiation of Suwannee River Fulvic Acid (SRFA) are shown to be ...
Stable organic species produced on irradiation of Suwannee River Fulvic Acid (SRFA) are shown to be ...
Fe(III)–oxalate complexes are likely abundant in clouds, fogs and aerosol water. They are photoreac...
Department of Chemistry, University of Rajasthan, Jaipur-302 004, India Manuscript received 7 Septem...