In a recent paper (Peerless et al. Nat. Chem. 15, 347-356, (2023)), the authors isolated the heterometallic cluster containing at its heart the prismatic {Bi6}-based cluster. To explain its exceptionally high abundance and selective formation tendency (as compared to other Zintl clusters) as well as the unusual magnetic-response properties, the authors introduced the so-called phi-aromaticity. Here, we show that introducing a new type of aromaticity in this case is unjustified and misleading
It is generally observed that quintessential aromatic compounds have delocalised electronic configur...
A systematic estimation of aromaticity in X3Y3H6, 1, (X = B, Al, Ga; Y = N, P, As), P3N3H6, 2, and X...
C-60 does not have "superaromatic'' or even aromatic character, but is a spherically pi antiaromatic...
The aromatic character of some small planar metallic clusters was revisited with an emphasis on thei...
Originally, the concepts of aromaticity and antiaromaticity were introduced to explain the stability...
After more than 150 years since the Kekule\u27s conceptualization of the benzene structure, this sma...
The chemical bonding of Zintl clusters is still an evolving and hot topic in modern chemistry. In th...
The planarity of small boron-based clusters is the result of an interplay between geometry, electron...
Osorio, E (Osorio, Edison). Univ Talca, Ctr Bioinformat & Simulac Mol, Talca, Chile[ 3 ]In this art...
Structural characterization of the discrete [Sn@Cu12@Sn20]12− cluster exposed a fascinating architec...
From the beginnings of boron cluster chemistry, it was recognized that their three-dimensional cage ...
Metallabenzenes are a class of molecules in which a CH unit in benzene is replaced by a functionaliz...
As shown by detailed nucleus-independent chemical shift (NICS) analyses of the contributions of each...
Amidst the general bonding patterns designed to explain stability aromaticity has leading role. Goin...
Author Institution: Department of Chemistry, Brown University, Providence, Rhode IslandPhotoelectron...
It is generally observed that quintessential aromatic compounds have delocalised electronic configur...
A systematic estimation of aromaticity in X3Y3H6, 1, (X = B, Al, Ga; Y = N, P, As), P3N3H6, 2, and X...
C-60 does not have "superaromatic'' or even aromatic character, but is a spherically pi antiaromatic...
The aromatic character of some small planar metallic clusters was revisited with an emphasis on thei...
Originally, the concepts of aromaticity and antiaromaticity were introduced to explain the stability...
After more than 150 years since the Kekule\u27s conceptualization of the benzene structure, this sma...
The chemical bonding of Zintl clusters is still an evolving and hot topic in modern chemistry. In th...
The planarity of small boron-based clusters is the result of an interplay between geometry, electron...
Osorio, E (Osorio, Edison). Univ Talca, Ctr Bioinformat & Simulac Mol, Talca, Chile[ 3 ]In this art...
Structural characterization of the discrete [Sn@Cu12@Sn20]12− cluster exposed a fascinating architec...
From the beginnings of boron cluster chemistry, it was recognized that their three-dimensional cage ...
Metallabenzenes are a class of molecules in which a CH unit in benzene is replaced by a functionaliz...
As shown by detailed nucleus-independent chemical shift (NICS) analyses of the contributions of each...
Amidst the general bonding patterns designed to explain stability aromaticity has leading role. Goin...
Author Institution: Department of Chemistry, Brown University, Providence, Rhode IslandPhotoelectron...
It is generally observed that quintessential aromatic compounds have delocalised electronic configur...
A systematic estimation of aromaticity in X3Y3H6, 1, (X = B, Al, Ga; Y = N, P, As), P3N3H6, 2, and X...
C-60 does not have "superaromatic'' or even aromatic character, but is a spherically pi antiaromatic...