(Table 1) Concentration of iridium at DSDP Hole 75-530A

The section recovered at Site 530 (Holes 530A and 530B) consists of eight sedimentary units and one basalt unit. The composition of the basalt recovered in Hole 530A is distinct from typical mid-ocean ridge basalts (MORBs) but is similar to that of Hawaiian tholeiites and basalt from the central part of Walvis Ridge. Throughout most of its history, the southern Angola Basin received large volumes of redeposited material in the form of turbidites and, most recently, debris-flow deposits. Most of this material was derived from Walvis Ridge to the south, but thickness trends of acoustic units suggest that some of the sediment was derived from the African continental margin to the east. The basal sedimentary unit (Albian to Santonian) at Site 530 contains 262 beds of black shale that are interbedded with green and red claystone. Black shale makes up less than 10% of the total section, but in two cores of early Turonian age, black shale beds compose about 50% of the section. The black shales contain up to 19% organic carbon (average of about 5%) that is mainly of autochthonous marine origin but with significant contributions from terrigenous organic matter. The origin of these more- and less-reduced interbedded lithologies with varying amounts and types of organic matter, and variable amounts of pelagic, hemipelagic, and turbiditic sediment is complex and cannot be explained by any one simple process. Many factors affecting the concentration of dissolved oxygen in the bottom waters of the Angola Basin varied throughout the middle Cretaceous to produce bottom-water conditions that fluctuated between mildly oxic and oxygen-deficient, but most of the time bottom-waters and sediment-interstitial waters were sufficiently oxic to permit the accumulation of red oxidized sediment. A relatively complete sedimentary record of the Cretaceous/Tertiary boundary was recovered within a sequence of mudstone and marlstone turbidites in Hole 530A. There is a significant increase in the concentration of iridium above background levels at the boundary. High concentrations of many other elements also occur within the same stratigraphic interval as the iridium anomaly. Furthermore, there is a marked decrease in CaCO3 in the Tertiary strata above the iridium anomaly which suggests that the production of shallow-water carbonate also may have been affected by whatever caused elevated concentrations of iridium and other elements. These observations are consistent with the asteroid-impact theory proposed to explain the worldwide occurrence of an iridium anomaly at the Cretaceous/Tertiary boundary. The Cenozoic history of the Angola Basin was controlled mainly by (1) restriction of bottom-water flow from the south by Walvis Ridge; (2) development of glaciation on Antarctica; (3) opening of circulation passages in the southern oceans; (4) rapid turnover of cold, nutrient-rich waters that resulted in high productivity of diatoms; (5) influx of terrigenous sediment mainly by turbidity currents; and (6) production and preservation of carbonate sediment. The most distinctive Cenozoic event recorded in the section at Site 530 is the beginning of extensive glaciation on Anarctica and concomitant initiation of modern thermohaline bottom-water circulation that is manifested as a middle Eocene to middle Oligocene unconformity or compressed section accompanied by a drastic decrease in accumulation of CaCO3. Diatom abundances in HPC cores from Walvis Ridge (Site 532) and Angola Basin (Hole 530B) indicate that Benguela upwelling in these areas began in the late Miocene, reached a peak in the late Pliocene to early Pleistocene, and declined thereafter. Short-term variations in sediment composition at Site 532 are manifested as cyclic variations in concentrations of clay, CaCO3, and organic carbon with average periodicities of about 30-60 k.y. The main variability that produced the cycles probably was the influx of terrigenous clastic material which diluted the CaCO3. The sediment at Site 532 also contains several percent organic carbon that is dominantly of marine origin, but with significant terrigenous components. Data from multichannel seismic, gravity, and magnetic surveys were used to define the regional stratigraphic and structural evolution of Walvis Ridge and adjacent Cape and Angola basins. Six structural provinces are recognized, four on Walvis Ridge and two additional provinces that correspond to the Cape and Angola basins. The two eastern structural provinces on Walvis Ridge are underlain by continental crust. The two western structural provinces are underlain by oceanic basement. Two main directions of faults are evident in seismic profiles, one trending N 10° and one trending N 60°. The N 60° trend corresponds to the general orientation of the northern and southern flanks of Walvis Ridge as well as to the dominant direction of fracture zones. During the first phase of separation of Africa from South America (ca. 120-130 m.y. ago), a voluminous mass of volcanics was emplaced simultaneous with the emplacement of basalt in the Parana Basin of Brazil and the Kaokoveld Region of South Africa. This period of volcanism also formed the series of seaward-dipping internal basement reflectors that are characteristic of the two structural provinces of Walvis Ridge. A system of fault blocks developed in the brittle upper part of the newly formed crust. During the second phase of rifting, which ended before late Aptian, more tilted fault blocks were created in the upper brittle stratified continental crust. Magnetic lineations in basement rocks in the Angola and Cape basins in the vicinity of Walvis Ridge are not distinct but suggest that oceanic crust began to be emplaced between 120 and 112 m.y. ago (Barremian to early Aptian). At least part of the oceanic crust of the central plateau of eastern Walvis Ridge (structural province 3) may have been emplaced before any oceanic crust formed in the adjacent basins. A ridge jump occurred during the late Aptian to early Albian in the southern part of the Angola Basin which translated the previously formed oceanic crust and its overlying evaporite deposits on the South American side. Several ridge jumps occurred on both sides of Walvis Ridge during the Late Cretaceous and early Tertiary to produce a 500-km-long segment of mid-ocean ridge