This volume contains the proceedings of the Combined 19th International Workshop on Expressiveness in Concurrency and the 9th Workshop on Structural Operational Semantics (EXPRESS/SOS 2012) which was held on September 3, 2012 in Newcastle upon Tyne, United Kingdom, as an affiliated workshop of CONCUR 2012, the 23th International Conference on Concurrency Theory.The EXPRESS workshops aim at bringing together researchers interested in the expressiveness of various formal systems and semantic notions, particularly in the field of concurrency. Their focus has traditionally been on the comparison between programming concepts (such as concurrent, functional, imperative, logic and object-oriented programming) and between mathematical models of com...