Application of open-air sensors is an attractive option for detecting switching over-voltages as their installation does not interfere with operation of the lines. Drawback is that coupling strengths are not known beforehand and cross-coupling between a sensor near one phase and other phase conductors or even to other circuits affects the recordings. Calibration of the coupling matrix between phase voltages and sensor signals can be realized by relating the power frequency component in the recorded signals to a priori assumed base of symmetric phase voltages. This paper establishes a method to quantify the different causes for measurement uncertainties. The coupling matrix cannot be completely reconstructed from measurements, enforcing mode...