This volume contains the proceedings of SOS 2011, the Eight Workshop on Structural Operational Semantics, held on the 5th of September 2011 in Aachen, Germany as an affiliated workshop of CONCUR 2011, the 22nd International Conference on Concurrency Theory. Structural operational semantics (SOS) provides a framework for giving operational semantics to programming and specification languages. A growing number of programming languages from commercial and academic spheres have been given usable semantic descriptions by means of structural operational semantics. Because of its intuitive appeal and flexibility, structural operational semantics has found considerable application in the study of the semantics of concurrent processes. It is also a ...