The purpose of this thesis is to support the optimization of the ‘exhaust-pipe’, or so-called ‘divertor’, of the nuclear fusion experiment ITER, a large international fusion reactor now under construction in the south of France. We focus particularly on two ‘tools’ for optimization of the plasma conditions in the divertor: electric fields and neutral particles. We look at how these ‘tools’ affect the plasma conditions at divertor surfaces. These conditions determine the type and rates of plasma-surface interaction processes and ultimately the lifetime of these surface materials. A plasma boundary phenomenon that can be changed by the presence of electric fields is the so-called ‘Debye sheath’. This is a voltage drop in the transition betwee...