Production and characterization of bio-oil from fluidized bed pyrolysis of olive stones, pinewood, and torrefied feedstock

Advancements in fluidized bed pyrolysis mechanisms and analytical methodologies are critical for progress in the biorefinery sector in general and the aviation fuel sector in particular. The statistical modelling of pyrolysis product yields and composition allowed us to observe advantages of operating temperature and feedstock selections over the torrefaction process and catalyst addition in a fluidized bed reactor. Results suggest that the chemical composition and physical properties of bio-oil from pyrolysis of olive stones at 600 degrees C and pinewood pellets at 500 degrees C are the most suitable for use as fuels. This work suggests that only combined use of selected gas chromatography mass spectroscopy, UV fluorescence, nuclear magnetic resonance spectroscopy, and rheology can provide comprehensive information on pyrolysis bio-oil composition. Importantly from a technological point of view, bio-oil was characterized i) by a viscosity similar to that of fossil-based oil; ii) by a low oxygen and water content; and iii) by a balanced composition of aliphatic and aromatic species. These factors indicate that bio-oil from fluidized bed pyrolysis of biomasses is a promising material for use in the aviation industry and energy production.The authors gratefully acknowledge financial support from Science Foundation Ireland (Grant number 16/SP/3829) and Arigna Fuels under the Sustainable Energy and Fuel Efficiency (SEFE) spoke of the Research Centre for Marine and Renewable Energy (MaREI). The authors gratefully acknowledge financial support (Grant number 731101) given by European Union's Horizon 2020 Research and Innovation Programme (BRISK II). Dr. Gerrit Ralf Surup from NTNU is acknowledged for technical support on Karl Fisher titration and elemental analysis