By combining the KMOC-formalism with the exponential representation of the scattering matrix we show that the two-body scattering angle is given by the corresponding matrix element of the exponential representation. This holds to all orders in the Post-Minkowskian expansion of gravity when restricted to the conservative sector. Once gravitational radiation is taken into account new terms correcting this relationship appear starting at fourth Post-Minkowskian order. A systematic expansion of the momentum kick is provided to any order, thus illustrating the iterative structure that partly recycles terms from lower orders in the Post-Minkowskian expansion. We provide explicit results for this computation to fourth Post-Minkowskian order, the f...