Thermal gelation of cellulose based suspensions

Funding Information: Open Access funding provided by Aalto University. J. K. acknowledges funding from Academy of Finland (308235). M. J. A., A. P. and J. K. acknowledge support from FinnCERES flagship (151830423), Business Finland (211835) and Future Makers (Älyä Vaahtoihin) programs. Publisher Copyright: © 2023, The Author(s).A more sustainable future calls for bio-based alternatives to replace plastic foams for various applications, such as packaging, insulation and cushioning. Some bio-based foams emerging in scientific publications are fabricated using liquid foam templating and methyl cellulose as well as fibers as main constituents. Scaling up of the production, however, requires a comprehensive understanding of the rheology of the foam during the shaping and drying processes. In this article, we report rheological studies of cellulose based systems in the context of thermal gelation. In more precise terms, we study how the presence of cellulose fibers and other additive materials influences the thermal gelation properties of methyl cellulose. We observe that the rheological properties, while heavily dependent on the material composition, are reasonably adjustable by appropriate material choices. The fibers are seen to decrease the temperature required for methyl cellulose to undergo a viscoelastic transition which is useful in the solid foam fabrication process. We anticipate that in the present application, the fibers increase the stability of the desired structure during the drying stage of the foam.Peer reviewe