Since the groundbreaking discovery in 2018 that the synthesis of a bottleable nucleophilic aluminyl anion is feasible, a handful of derivatives have been developed to date, which are, however, limited to diamino- and dialkyl-substituted species. Herein, we report the synthesis of a cyclic (alkyl)(amino)aluminyl anion based on a five-membered framework. The dicoordinate aluminum center features both a lone pair of electrons and an unoccupied 3p orbital, thus genuinely making it isoelectronic with carbenes. We show the bond formation and bond activation at the Al sphere: thus, not only does it undergo electron redistribution with borane to furnish a heteroatomic group 13 ring exhibiting a σ-aromatic nature concomitant with a three-center two-...
The work detailed in this thesis describes the synthesis and reactivity of an N-heterocyclic aluminy...
Homodinuclear multiple-bonded neutral Al compounds, aluminum analogues of alkenes, have been a notor...
Homodinuclear multiple-bonded neutral Al compounds, aluminum analogues of alkenes, have been a notor...
The anionic aluminum(I) species, namely aluminyl anion, is a new class of low-valent aluminum specie...
The reactivity of aluminium compounds is dominated by their electron deficiency and consequent elect...
The reactivity of aluminium compounds is dominated by their electron deficiency and consequent elect...
The reactivity of aluminium compounds is dominated by their electron deficiency and consequent elect...
The synthesis and structure of an anionic aluminabenzene, which is the first example of an aluminum-...
The synthesis and structure of an anionic aluminabenzene, which is the first example of an aluminum-...
Trivalent aluminium compounds are well known for their reactivity as Lewis acids/electrophiles, a fe...
Trivalent aluminium compounds are well known for their reactivity as Lewis acids/electrophiles, a fe...
Since aluminum is the most electropositive element among the p-block elements, the construction of m...
The work detailed in this thesis describes the synthesis and reactivity of an N-heterocyclic aluminy...
The work detailed in this thesis describes the synthesis and reactivity of an N-heterocyclic aluminy...
The work detailed in this thesis describes the synthesis and reactivity of an N-heterocyclic aluminy...
The work detailed in this thesis describes the synthesis and reactivity of an N-heterocyclic aluminy...
Homodinuclear multiple-bonded neutral Al compounds, aluminum analogues of alkenes, have been a notor...
Homodinuclear multiple-bonded neutral Al compounds, aluminum analogues of alkenes, have been a notor...
The anionic aluminum(I) species, namely aluminyl anion, is a new class of low-valent aluminum specie...
The reactivity of aluminium compounds is dominated by their electron deficiency and consequent elect...
The reactivity of aluminium compounds is dominated by their electron deficiency and consequent elect...
The reactivity of aluminium compounds is dominated by their electron deficiency and consequent elect...
The synthesis and structure of an anionic aluminabenzene, which is the first example of an aluminum-...
The synthesis and structure of an anionic aluminabenzene, which is the first example of an aluminum-...
Trivalent aluminium compounds are well known for their reactivity as Lewis acids/electrophiles, a fe...
Trivalent aluminium compounds are well known for their reactivity as Lewis acids/electrophiles, a fe...
Since aluminum is the most electropositive element among the p-block elements, the construction of m...
The work detailed in this thesis describes the synthesis and reactivity of an N-heterocyclic aluminy...
The work detailed in this thesis describes the synthesis and reactivity of an N-heterocyclic aluminy...
The work detailed in this thesis describes the synthesis and reactivity of an N-heterocyclic aluminy...
The work detailed in this thesis describes the synthesis and reactivity of an N-heterocyclic aluminy...
Homodinuclear multiple-bonded neutral Al compounds, aluminum analogues of alkenes, have been a notor...
Homodinuclear multiple-bonded neutral Al compounds, aluminum analogues of alkenes, have been a notor...