Unlocking full and fast conversion in photocatalytic carbon dioxide reduction for applications in radio-carbonylation
- Serena Monticelli
- Alex Talbot
- Philipp Gotico
- Fabien Caillé
- Olivier Loreau
- Antonio Del Vecchio
- Augustin Malandain
- Antoine Sallustrau
- Winfried Leibl
- Ally Aukauloo
- Frédéric Taran
- Zakaria Halime
- Davide Audisio
DOIAbstract
Abstract Harvesting sunlight to drive carbon dioxide (CO2) valorisation represents an ideal concept to support a sustainable and carbon-neutral economy. While the photochemical reduction of CO2 to carbon monoxide (CO) has emerged as a hot research topic, the full CO2-to-CO conversion remains an often-overlooked criterion that prevents a productive and direct valorisation of CO into high-value-added chemicals. Herein, we report a photocatalytic process that unlocks full and fast CO2-to-CO conversion (<10 min) and its straightforward valorisation into human health related field of radiochemistry with carbon isotopes. Guided by reaction-model-based kinetic simulations to rationalize reaction optimisations, this manifold opens new opportunities...
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