Add to ORKGo-Nitrosobenzaldehyde is a reactive intermediate useful in the synthesis of nitrogen heterocycles. Previous strategies for using o-nitrosobenzaldehyde involve its isolation via chromatography and/or formation under harsh conditions. Herein, this intermediate was photochemically generated in situ from o-nitrobenzyl alcohols in a mild, efficient manner for the construction of 1,2-dihydro-3 H-indazol-3-ones using an aqueous solvent at room temperature. This convenient reaction offers several advantages over reported methods. The commercially available photoreactor employed 3 × 18 W bulbs outputting broad emission above 365 nm
Whereas 2H-benztriazoles are photochemically stable, I H-benztriazoles yield biradicals after splitt...
A diverse reactivity of diazo compounds with nitrosoarene in an oxygen-transfer process and a formal...
The synthesis of indazolo[2,3-<i>a</i>]quinoline derivatives in moderate to good yields from 2-(2-ni...
o-Nitrosobenzaldehyde is a reactive intermediate useful in the synthesis of nitrogen heterocycles. P...
The Davis-Beirut reaction provides access to 2H-indazoles from aromatic nitro compounds. However, N-...
Tetrabutylammonium decatungstate (TBADT) has emerged as a valuable photocatalyst for sunlight-induce...
Indazoles are an important class of nitrogen heterocycles because of their excellent performance in ...
A facile one-pot two-stage photochemical synthesis of aromatic azoxy compounds and imines has been d...
Nitrosocarbonyl intermediates are photochemically generated from 1,2,4-oxadiazole-4-oxides and effic...
2019-05-02Organic photochemical reactions can be used to synthesize a wide array of compounds. Often...
The synthesis of N2-aryl 1,2,3-triazoles from 2,5-disubstituted tetrazoles was achieved under photoc...
Whereas 2H-benztriazoles are photochemically stable, 1H-benztriazoles yield biradicals after splitin...
We have demonstrated that the 3-diethylaminobenzyl (DEABn) photolabile protecting group (PPG) is an ...
We describe a photo-induced reaction for the in situ generation of highly reactive alkyl diazo compo...
Photochemical reactions of azo and triazo derivatives of mesoionic 1,3-diphenyltetrazolium heterocyc...
Whereas 2H-benztriazoles are photochemically stable, I H-benztriazoles yield biradicals after splitt...
A diverse reactivity of diazo compounds with nitrosoarene in an oxygen-transfer process and a formal...
The synthesis of indazolo[2,3-<i>a</i>]quinoline derivatives in moderate to good yields from 2-(2-ni...
o-Nitrosobenzaldehyde is a reactive intermediate useful in the synthesis of nitrogen heterocycles. P...
The Davis-Beirut reaction provides access to 2H-indazoles from aromatic nitro compounds. However, N-...
Tetrabutylammonium decatungstate (TBADT) has emerged as a valuable photocatalyst for sunlight-induce...
Indazoles are an important class of nitrogen heterocycles because of their excellent performance in ...
A facile one-pot two-stage photochemical synthesis of aromatic azoxy compounds and imines has been d...
Nitrosocarbonyl intermediates are photochemically generated from 1,2,4-oxadiazole-4-oxides and effic...
2019-05-02Organic photochemical reactions can be used to synthesize a wide array of compounds. Often...
The synthesis of N2-aryl 1,2,3-triazoles from 2,5-disubstituted tetrazoles was achieved under photoc...
Whereas 2H-benztriazoles are photochemically stable, 1H-benztriazoles yield biradicals after splitin...
We have demonstrated that the 3-diethylaminobenzyl (DEABn) photolabile protecting group (PPG) is an ...
We describe a photo-induced reaction for the in situ generation of highly reactive alkyl diazo compo...
Photochemical reactions of azo and triazo derivatives of mesoionic 1,3-diphenyltetrazolium heterocyc...
Whereas 2H-benztriazoles are photochemically stable, I H-benztriazoles yield biradicals after splitt...
A diverse reactivity of diazo compounds with nitrosoarene in an oxygen-transfer process and a formal...
The synthesis of indazolo[2,3-<i>a</i>]quinoline derivatives in moderate to good yields from 2-(2-ni...