An optimized multigram-scale route to phototropone (bicyclo[3.2.0]hepta-2,6-dien-7-one) is reported via the 4-π-photocyclization of tropone complexed to Lewis acid. Phototropone is a highly versatile molecular building block, and its conversion into 18 novel derivatives using standard transformations is demonstrated, allowing access to a variety of rigid bicyclic scaffolds
The use of light as activation mode for organic molecules is surely one of the oldest concepts in th...
[2+2]-Photocycloaddition is a powerful method to synthesise highly strained, complex and multicyclic...
1,4-Functionalisation of cyclohepta-l,3-diene using a nitroso-cycloaddition strategy provided precur...
This thesis describes the synthesis of novel [3.2.0]bicycles via 4-π-photocyclisation of tropone and...
Bicyclic amines are important motifs for the preparation of bioactive materials. These species have ...
The synthesis of substituted non-symmetric tropones has proven to be a considerable synthetic challe...
The application of quinone-derived substrates as building blocks for the synthesis of tropolonoid na...
A modular synthetic platform for the synthesis of the multi-bioactive sesquiterpene-tropolone natura...
This minireview highlights the scope of 4‐π‐photocyclizations (photoinduced electrocyclizations that...
Providing non-traditional disconnections has been recently highlighted as one of the “Key messages f...
Abstract- Three photochemical methods aiming primarily at syntheses of cyclopentanoid natural produc...
Photoredox catalysis has transformed the landscape of radical-based synthetic chemistry. Additions o...
Intramolecular photochemical [2 + 2]-cyclization of acetophenone enamides gave 2-azabicyclo[3.2.0]h...
This thesis is a continuation of the work by Bathate, which had shown that intramolecular cyclisatio...
The use of visible light to activate transition metal catalysts towards redox processes has transfor...
The use of light as activation mode for organic molecules is surely one of the oldest concepts in th...
[2+2]-Photocycloaddition is a powerful method to synthesise highly strained, complex and multicyclic...
1,4-Functionalisation of cyclohepta-l,3-diene using a nitroso-cycloaddition strategy provided precur...
This thesis describes the synthesis of novel [3.2.0]bicycles via 4-π-photocyclisation of tropone and...
Bicyclic amines are important motifs for the preparation of bioactive materials. These species have ...
The synthesis of substituted non-symmetric tropones has proven to be a considerable synthetic challe...
The application of quinone-derived substrates as building blocks for the synthesis of tropolonoid na...
A modular synthetic platform for the synthesis of the multi-bioactive sesquiterpene-tropolone natura...
This minireview highlights the scope of 4‐π‐photocyclizations (photoinduced electrocyclizations that...
Providing non-traditional disconnections has been recently highlighted as one of the “Key messages f...
Abstract- Three photochemical methods aiming primarily at syntheses of cyclopentanoid natural produc...
Photoredox catalysis has transformed the landscape of radical-based synthetic chemistry. Additions o...
Intramolecular photochemical [2 + 2]-cyclization of acetophenone enamides gave 2-azabicyclo[3.2.0]h...
This thesis is a continuation of the work by Bathate, which had shown that intramolecular cyclisatio...
The use of visible light to activate transition metal catalysts towards redox processes has transfor...
The use of light as activation mode for organic molecules is surely one of the oldest concepts in th...
[2+2]-Photocycloaddition is a powerful method to synthesise highly strained, complex and multicyclic...
1,4-Functionalisation of cyclohepta-l,3-diene using a nitroso-cycloaddition strategy provided precur...
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