Generalised linear response theory for the full quantum work statistics

We consider a quantum system driven out of equilibrium via a small Hamiltonian perturbation. Building on the paradigmatic framework of linear response theory, we derive an expression for the full generating function of the dissipated work. Remarkably, we find that all information about the distribution can be encoded in a single accessible quantity known as the relaxation function, thus opening up new ways to use phenomenological models to study non-equilibrium fluctuations in complex quantum systems. Our results establish a number of refined thermodynamic constraints on the work statistics that apply to regimes of small but arbitrarily fast protocols, and do not require assumptions such as slow driving or weak coupling to an environment. Finally, our approach uncovers a distinctly quantum signature in the work statistics that originates from underlying zero-point energy fluctuations. This causes an increased dispersion of the probability distribution at short driving times, a feature that can be probed in efforts to witness non-classical effects in quantum thermodynamics.Comment: 11 pages, one figure. Comments welcom