Add to ORKGChelated aluminumalkoxides have been prepared from the reaction of aluminum-secbutoxide with acetylacetone (AcAc) or ethylacetoacetate (EAA) in different alkoxide/chelating agent molar ratios. These compounds have been used to study the possibility of controlling the rate of hydrolysis of aluminumalkoxides and/or the polycondensation of the related hydroxides. Hydrolysis was followed by NIR-spectroscopy and showed no differences for chelated aluminum-secbutoxide and the pure alkoxide. In contrast the polycondensation of aluminumhydroxides chelated with ethylacetoacetate decreased remarkably and depends on the alkoxide/chelating agent molar ratio
Aluminum oxides and hydroxides are widely applied because of the great variety of their modification...
Department of Chemstry, Southern University, New Orleans, Louisiana 70126, U.S.A. Manuscript receiv...
The XRD and DTA methods were used to examine changes in the phase composition and morphology of alum...
Chelated aluminumalkoxides have been prepared from the reaction of aluminum-secbutoxide with acetyla...
Abstract--Chelating or anic acids hampered the hydrolytic reactions of A1 and affected the nature of...
Reactive aluminum alkoxide (ASB, aluminium sec-butoxide) was chelated using β-diketone (EAA, ethyl a...
Chelating agent, such as acetylacetone (AcAcH) and ethylacetoacetate (EAA) are used to avoid the und...
Reactions of primary, secondary, and tertiary alkoxiden of aluminium with acetyl chloride have been ...
Aluminum alkoxides are moderately active in promoting the ethoxylation of fatty alcohols. When these...
Representative amino acids, carboxylic acids, a ketone, hydrox-amic acids, 3-hydroxypyridinones and ...
Alkoxide-based molecular routes used as single-source precursors for the synthesis of ultrafine mate...
Amorphous aluminum compounds are formed during the synthesis of the γ-Al2O3 catalyst precursor...
This paper summarizes recent literature data and presents new experimental data on the mechanisms of...
Acidic and basic properties of the surface of aluminum oxides, whose precursors are electrochemicall...
Aluminum oxides and hydroxides are widely applied because of the great variety of their modification...
Aluminum oxides and hydroxides are widely applied because of the great variety of their modification...
Department of Chemstry, Southern University, New Orleans, Louisiana 70126, U.S.A. Manuscript receiv...
The XRD and DTA methods were used to examine changes in the phase composition and morphology of alum...
Chelated aluminumalkoxides have been prepared from the reaction of aluminum-secbutoxide with acetyla...
Abstract--Chelating or anic acids hampered the hydrolytic reactions of A1 and affected the nature of...
Reactive aluminum alkoxide (ASB, aluminium sec-butoxide) was chelated using β-diketone (EAA, ethyl a...
Chelating agent, such as acetylacetone (AcAcH) and ethylacetoacetate (EAA) are used to avoid the und...
Reactions of primary, secondary, and tertiary alkoxiden of aluminium with acetyl chloride have been ...
Aluminum alkoxides are moderately active in promoting the ethoxylation of fatty alcohols. When these...
Representative amino acids, carboxylic acids, a ketone, hydrox-amic acids, 3-hydroxypyridinones and ...
Alkoxide-based molecular routes used as single-source precursors for the synthesis of ultrafine mate...
Amorphous aluminum compounds are formed during the synthesis of the γ-Al2O3 catalyst precursor...
This paper summarizes recent literature data and presents new experimental data on the mechanisms of...
Acidic and basic properties of the surface of aluminum oxides, whose precursors are electrochemicall...
Aluminum oxides and hydroxides are widely applied because of the great variety of their modification...
Aluminum oxides and hydroxides are widely applied because of the great variety of their modification...
Department of Chemstry, Southern University, New Orleans, Louisiana 70126, U.S.A. Manuscript receiv...
The XRD and DTA methods were used to examine changes in the phase composition and morphology of alum...