The synthesis and isolation of gold(I) precatalysts often requires the generation of several isolable intermediates as well as numerous purification steps. New protocols for the expedient synthesis of neutral [Au(OH)(NHC)] and [Au(CH2COCH3)(NHC)] species from [AuCl(NHC)] or [AuCl(DMS)] precursors bearing a variety of N-heterocyclic carbene (NHC) ligands are presented. These methods can be employed in a telescoping manner for the synthesis of catalytically relevant [Au(NTf2)(NHC)] and [Au(NHC)(NCCH3)]-[BF4] complexes. These attractive methods are straightforward and practical leading to various complexes in high isolated yields and purity.The synthesis and isolation of gold(I) precatalysts often requires the generation of several isolable in...
A new synthetic strategy was devised leading to the formation of complexes, such as [Au(IPr)(CH2COCH...
The fields of N-heterocyclic carbenes and homogeneous gold catalysis have experienced tremendous gro...
A number of cationic gold(I) complexes have been synthesized and found to be stabilized by the use o...
The synthesis and isolation of gold(I) precatalysts often requires the generation of several isolabl...
The synthesis and isolation of gold(I) precatalysts often requires the generation of several isolabl...
The synthesis and isolation of gold(I) precatalysts often requires the generation of several isolab...
The European Research Council (ERC) and the Engineering and Physical Sciences Research Council (EPSR...
Gold has emerged as a powerful synthetic tool in the chemist's arsenal. From the early use of inorga...
Gold has emerged as a powerful synthetic tool in the chemist's arsenal. From the early use of inorga...
The development of procedures for the synthesis of valuable organic molecules constitutes an importa...
Gold has emerged as a powerful synthetic tool in the chemist's arsenal. From the early use of inorga...
The discovery of sustainable and scalable synthetic protocols leading to gold-aryl compounds bearing...
A new synthetic strategy was devised leading to the formation of complexes, such as [Au(IPr)(CH2COCH...
The discovery of sustainable and scalable synthetic protocols leading to gold-aryl compounds bearing...
The development of procedures for the synthesis of valuable organic molecules constitutes an importa...
A new synthetic strategy was devised leading to the formation of complexes, such as [Au(IPr)(CH2COCH...
The fields of N-heterocyclic carbenes and homogeneous gold catalysis have experienced tremendous gro...
A number of cationic gold(I) complexes have been synthesized and found to be stabilized by the use o...
The synthesis and isolation of gold(I) precatalysts often requires the generation of several isolabl...
The synthesis and isolation of gold(I) precatalysts often requires the generation of several isolabl...
The synthesis and isolation of gold(I) precatalysts often requires the generation of several isolab...
The European Research Council (ERC) and the Engineering and Physical Sciences Research Council (EPSR...
Gold has emerged as a powerful synthetic tool in the chemist's arsenal. From the early use of inorga...
Gold has emerged as a powerful synthetic tool in the chemist's arsenal. From the early use of inorga...
The development of procedures for the synthesis of valuable organic molecules constitutes an importa...
Gold has emerged as a powerful synthetic tool in the chemist's arsenal. From the early use of inorga...
The discovery of sustainable and scalable synthetic protocols leading to gold-aryl compounds bearing...
A new synthetic strategy was devised leading to the formation of complexes, such as [Au(IPr)(CH2COCH...
The discovery of sustainable and scalable synthetic protocols leading to gold-aryl compounds bearing...
The development of procedures for the synthesis of valuable organic molecules constitutes an importa...
A new synthetic strategy was devised leading to the formation of complexes, such as [Au(IPr)(CH2COCH...
The fields of N-heterocyclic carbenes and homogeneous gold catalysis have experienced tremendous gro...
A number of cationic gold(I) complexes have been synthesized and found to be stabilized by the use o...