The hybrid organo-inorganic compounds [Cu4(bipy)4V4O11(PO4)2]nH2O (n 5) (1), [Cu2(phen)2(PO4)(H2PO4)2(VO2) Æ 2H2O] (2) and [Cu2(phen)2(O3PCH2PO3)(V2O5) (H2O)]H2O (3) which present different bridging forms of the phosphate/phosphonate group, show different bulk magnetic properties. We herein analyze the magnetic behaviour of these compounds in terms of their structural parameters. We also report a theoretical study for compound (1) assuming four different magnetic exchange pathways between the copper centres present in the tetranuclear unit. For compound (1) the following J values were obtained J1 = +3.29; J2 = 0.63; J3 = 2.23; J4 = 46.14 cm 1. Compound (2) presents a Curie–Weiss behaviour in the whole range of temperature (3–...
International audienceTwo new layered copper hybrid materials, namely, the copper thiophene-2,5-diph...
International audienceTwo new layered copper hybrid materials, namely, the copper thiophene-2,5-diph...
International audienceTwo new layered copper hybrid materials, namely, the copper thiophene-2,5-diph...
Hydrothermal synthesis has allowed us to isolate and characterize three new inorganic organic hybrid...
The structure and magnetic properties of two hybrid VPO compounds [(Cu(2)bipy(2))(2)V4O11(PO4)(2)]ce...
The structure and magnetic properties of two hybrid VPO compounds [(Cu(2)bipy(2))(2)V4O11(PO4)(2)]ce...
Compound CU2(H2O)(2){O3PCH2N(C2H4)(2)NCH2PO3} (1) has a pillared layered structure in which the orga...
The syntheses, structural characterization, and magnetic behavior of two new hexanuclear copper(II)...
International audienceTwo new layered copper hybrid materials, namely, the copper thiophene-2,5-diph...
International audienceTwo new layered copper hybrid materials, namely, the copper thiophene-2,5-diph...
International audienceTwo new layered copper hybrid materials, namely, the copper thiophene-2,5-diph...
International audienceTwo new layered copper hybrid materials, namely, the copper thiophene-2,5-diph...
International audienceTwo new layered copper hybrid materials, namely, the copper thiophene-2,5-diph...
International audienceTwo new layered copper hybrid materials, namely, the copper thiophene-2,5-diph...
International audienceTwo new layered copper hybrid materials, namely, the copper thiophene-2,5-diph...
International audienceTwo new layered copper hybrid materials, namely, the copper thiophene-2,5-diph...
International audienceTwo new layered copper hybrid materials, namely, the copper thiophene-2,5-diph...
International audienceTwo new layered copper hybrid materials, namely, the copper thiophene-2,5-diph...
Hydrothermal synthesis has allowed us to isolate and characterize three new inorganic organic hybrid...
The structure and magnetic properties of two hybrid VPO compounds [(Cu(2)bipy(2))(2)V4O11(PO4)(2)]ce...
The structure and magnetic properties of two hybrid VPO compounds [(Cu(2)bipy(2))(2)V4O11(PO4)(2)]ce...
Compound CU2(H2O)(2){O3PCH2N(C2H4)(2)NCH2PO3} (1) has a pillared layered structure in which the orga...
The syntheses, structural characterization, and magnetic behavior of two new hexanuclear copper(II)...
International audienceTwo new layered copper hybrid materials, namely, the copper thiophene-2,5-diph...
International audienceTwo new layered copper hybrid materials, namely, the copper thiophene-2,5-diph...
International audienceTwo new layered copper hybrid materials, namely, the copper thiophene-2,5-diph...
International audienceTwo new layered copper hybrid materials, namely, the copper thiophene-2,5-diph...
International audienceTwo new layered copper hybrid materials, namely, the copper thiophene-2,5-diph...
International audienceTwo new layered copper hybrid materials, namely, the copper thiophene-2,5-diph...
International audienceTwo new layered copper hybrid materials, namely, the copper thiophene-2,5-diph...
International audienceTwo new layered copper hybrid materials, namely, the copper thiophene-2,5-diph...
International audienceTwo new layered copper hybrid materials, namely, the copper thiophene-2,5-diph...
International audienceTwo new layered copper hybrid materials, namely, the copper thiophene-2,5-diph...