Add to ORKGIn situ generated osmium-diamine chelates from 2,3-diaminopropionic acid or diaminosuccinic acid represent efficient catalysts for the highly productive aminohydroxylation of alkenes. The reaction can be employed with various osmium salts and successful catalyst recycling was demonstrated for a representative example. The catalyst design derives from the general structural features of recently investigated osmium complexes from alkene diamination reaction
Palladium catalysis enables the regioselective difunctionalization of alkenes using saccharin as ...
287-291For the first time, heterogeneous osmium tetroxide catalyzed asymmetric aminohydroxylation o...
The use of N-sulfonyloxy carbamates as reoxidants for the tethered aminohydroxylation (TA) reaction ...
In situ generated osmium-diamine chelates from 2,3-diaminopropionic acid or diaminosuccinic acid rep...
The aminohydroxylation reaction of olefins is a key organic transformation reaction, typically carri...
The first examples of amide-tethered aminohydroxylation reactions, catalyzed by osmium, showing that...
The cis dihydroxylation of alkenes is most efficiently accomplished by reaction with osmium tetroxid...
The osmium-mediated aminohydroxylation reaction is a powerful oxidation that introduces a hydroxyl g...
A new catalyst derived from osmium has been prepared, fully characterized and tested in the dihydrox...
For the synthesis of the 1,2-diols, <i>cis</i>-1,2-dihydroxylation of alkenes catalyzed by osmium(V...
Homogeneous catalysis by osmium complexes is more promising than hitherto realized. Most of the reac...
This review highlights key aspects of the Tethered Aminohydroxylation from its discovery to its curr...
The tethered aminohydroxylation of cyclic allylic carbamates is described using catalytic amounts of...
By using a bis(quinidinyl)phthalazine derivative linked to an insoluble organic polymer, 87% e.e. wa...
[reaction: see text] Changing the identity of the N leaving group on a hydroxylamine-based reoxidant...
Palladium catalysis enables the regioselective difunctionalization of alkenes using saccharin as ...
287-291For the first time, heterogeneous osmium tetroxide catalyzed asymmetric aminohydroxylation o...
The use of N-sulfonyloxy carbamates as reoxidants for the tethered aminohydroxylation (TA) reaction ...
In situ generated osmium-diamine chelates from 2,3-diaminopropionic acid or diaminosuccinic acid rep...
The aminohydroxylation reaction of olefins is a key organic transformation reaction, typically carri...
The first examples of amide-tethered aminohydroxylation reactions, catalyzed by osmium, showing that...
The cis dihydroxylation of alkenes is most efficiently accomplished by reaction with osmium tetroxid...
The osmium-mediated aminohydroxylation reaction is a powerful oxidation that introduces a hydroxyl g...
A new catalyst derived from osmium has been prepared, fully characterized and tested in the dihydrox...
For the synthesis of the 1,2-diols, <i>cis</i>-1,2-dihydroxylation of alkenes catalyzed by osmium(V...
Homogeneous catalysis by osmium complexes is more promising than hitherto realized. Most of the reac...
This review highlights key aspects of the Tethered Aminohydroxylation from its discovery to its curr...
The tethered aminohydroxylation of cyclic allylic carbamates is described using catalytic amounts of...
By using a bis(quinidinyl)phthalazine derivative linked to an insoluble organic polymer, 87% e.e. wa...
[reaction: see text] Changing the identity of the N leaving group on a hydroxylamine-based reoxidant...
Palladium catalysis enables the regioselective difunctionalization of alkenes using saccharin as ...
287-291For the first time, heterogeneous osmium tetroxide catalyzed asymmetric aminohydroxylation o...
The use of N-sulfonyloxy carbamates as reoxidants for the tethered aminohydroxylation (TA) reaction ...