For an important class of organic reactions in which a fragment of the reactants, the leaving group (LG) or nucleofuge (Z), is detached of the substrate bearing the bonding electron pair, the global electrophilicity index of the CH(3)LG system is proposed as a reliable descriptor of the intrinsic nucleofugality of the LG. The model is illustrated by ranking within a unique relative scale, the LG ability of 28 functional groups commonly involved in substitution and elimination reactions in organic chemistry
(Chemical Equation Presented) Nucleophilic substitution is ubiquitous in chemistry and well studied....
The leaving group ability (nucleofugality) of the pentafluorophenolate anion has been determined fro...
The global electrophilicity power, ω, of a series of dipoles and dipolarophiles commonly used in 1,3...
For an important class of organic reactions in which a fragment of the reactants, the leaving group ...
We propose and test an empirical nucleofugality index to rank the leaving group ability of a series ...
In this short authors' review, a method for determining experimental and calculated nucleofugalities...
Publicación ISIWe propose that a specific property of a chemical fragment, its regional electrophili...
Publicación ISIWe propose that a specific property of a chemical fragment, its regional electrophili...
In this short authors' review, a method for determining experimental and calculated nucleofugalities...
In this short authors\u27 review, a method for determining experimental and calculated nucleofugalit...
In this short authors\u27 review, a method for determining experimental and calculated nucleofugalit...
We propose and test a new reactivity index tentatively called homofugality, to quantitatively rank t...
We propose and test a new reactivity index tentatively called homofugality, to quantitatively rank t...
Theoretical electrophilicity and nucleophilicity scales, defined in terms of electronic reactivity i...
In the light of the generalized philicity concept, intermolecular reactivity of some selected system...
(Chemical Equation Presented) Nucleophilic substitution is ubiquitous in chemistry and well studied....
The leaving group ability (nucleofugality) of the pentafluorophenolate anion has been determined fro...
The global electrophilicity power, ω, of a series of dipoles and dipolarophiles commonly used in 1,3...
For an important class of organic reactions in which a fragment of the reactants, the leaving group ...
We propose and test an empirical nucleofugality index to rank the leaving group ability of a series ...
In this short authors' review, a method for determining experimental and calculated nucleofugalities...
Publicación ISIWe propose that a specific property of a chemical fragment, its regional electrophili...
Publicación ISIWe propose that a specific property of a chemical fragment, its regional electrophili...
In this short authors' review, a method for determining experimental and calculated nucleofugalities...
In this short authors\u27 review, a method for determining experimental and calculated nucleofugalit...
In this short authors\u27 review, a method for determining experimental and calculated nucleofugalit...
We propose and test a new reactivity index tentatively called homofugality, to quantitatively rank t...
We propose and test a new reactivity index tentatively called homofugality, to quantitatively rank t...
Theoretical electrophilicity and nucleophilicity scales, defined in terms of electronic reactivity i...
In the light of the generalized philicity concept, intermolecular reactivity of some selected system...
(Chemical Equation Presented) Nucleophilic substitution is ubiquitous in chemistry and well studied....
The leaving group ability (nucleofugality) of the pentafluorophenolate anion has been determined fro...
The global electrophilicity power, ω, of a series of dipoles and dipolarophiles commonly used in 1,3...